5,5-dimethyl-3-[(2-nitrophenyl)methoxy]cyclohex-2-en-1-one | 1450999-15-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,5-dimethyl-3-[(2-nitrophenyl)methoxy]cyclohex-2-en-1-one
• CAS: 1450999-15-1
• 化学式: C₁₅H₁₇NO₄
• 分子量: 275.304
• InChiKey: SMGRKUBGCYDVSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  72.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  邻硝基苯甲醇 、 5,5-二甲基-1,3-环己二酮 在 potassium dodeca tungstocobaltate trihydrate 作用下， 以 neat (no solvent) 为溶剂， 反应 1.17h， 以82%的产率得到5,5-dimethyl-3-[(2-nitrophenyl)methoxy]cyclohex-2-en-1-one
  参考文献：
  名称：

  醇与环状和无环1,3-二羰基化合物反应中的不同产物：K5CoW12O40作为电子转移纳米催化剂

  摘要：

  摘要K5CoW12O40被用作1,3-二羰基化合物苄基化的高效催化剂。当在这种条件下使用环状1,3-二羰基化合物代替线性化合物时，可获得β-酮烯醇醚。本方法提供了一种实用，简单，温和，环保且省时的醚化方法。催化剂的极低负载，易于后处理，易于处理以及催化剂的可重复使用性是该催化剂的其他优点。

  DOI：

  10.1016/j.cclet.2012.10.011

文献信息

• Rafiee, Ezzat; Kahrizi, Masoud, South African Journal of Chemistry, 2013, vol. 66, p. 145 - 149
  作者：Rafiee, Ezzat、Kahrizi, Masoud

  DOI：——

  日期：——
• TW2019/36562
  申请人：——

  公开号：——

  公开（公告）日：——
• PHOTOLABILE BETA-DICARBONYL COMPOUNDS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20200354484A1

  公开（公告）日：2020-11-12

  The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization
• [EN] PHOTOLABILE BETA-DICARBONYL COMPOUNDS<br/>[FR] COMPOSÉS DE BÊTA-DICARBONYLE PHOTOLABILES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2019152267A1

  公开（公告）日：2019-08-08

  The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization
• [EN] METHOD OF DISPOSING AN ADHESIVE ONTO A SUBSTRATE AND ARTICLE<br/>[FR] PROCÉDÉ DE DISPOSITION D'UN ADHÉSIF SUR UN SUBSTRAT ET ARTICLE
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2021019353A1

  公开（公告）日：2021-02-04

  A method of disposing an adhesive composition onto a first surface of a first substrate comprises: a) disposing a photoactivatable adhesive precursor composition onto at least a portion of the first surface of the first substrate according to a predetermined pattern, and b) exposing the photoactivatable adhesive precursor composition to actinic electromagnetic radiation, thereby providing an adhesive precursor composition that spontaneously cures to provide the adhesive composition. The photoactivatable adhesive precursor composition comprises: at least one free-radically polymerizable compound and a photoactivatable redox initiation system comprising: (i) at least one photoactivatable reducing agent precursor; (ii) at least one transition metal compound comprising at least one metal selected from groups 5 to 11 in the Periodic Table of the Elements; (iii) optional organic peroxide; and (iv) optional quaternary ammonium halide. An article preparable according to the method is also disclosed.