| 183118-58-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• CAS: 183118-58-3
• 化学式: C₁₁H₁₆O₂Si
• 分子量: 208.332
• InChiKey: LQNOJYWSILZOCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.28
• 重原子数：
  14.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  22.37
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  以 四氢呋喃 、 乙腈 为溶剂， 85.0 ℃ 、999.99 MPa 条件下， 反应 45.0h， 以47%的产率得到endo-3,12-dioxatetracyclo[7.2.1.0^1,70^5,7]dodec-10-ene
  参考文献：
  名称：

  Intramolecular Diels-Alder reactions of furans with a merely strain-activated tetrasubstituted alkene: Bicyclopropylidene

  摘要：

  Bicyclopropylidene derivatives 1, 6, 8 with furan moieties attached on tethers of various length and nature all undergo clean intramolecular Diels-Alder reactions with complete endo-diastereoselectivities when heated to 70 - 130 degrees C, under 10 kbar pressure. The reaction rates are at]east as high or higher than those of analogously tethered methylenecyclopropane-furan derivatives 15, 17, 20, in spite of the fact that the reactive double bond in bicyclopropylidene is tetrasubstituted and not activated by any electron withdrawing group. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0040-4020(96)00720-x
• 作为产物：
  描述：

  (2-亚甲基环丙基)甲醇 、 Chlor-2-furanyl-dimethylsilan 在 三乙胺 作用下， 以 乙醚 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Intramolecular Diels-Alder reactions of furans with a merely strain-activated tetrasubstituted alkene: Bicyclopropylidene

  摘要：

  Bicyclopropylidene derivatives 1, 6, 8 with furan moieties attached on tethers of various length and nature all undergo clean intramolecular Diels-Alder reactions with complete endo-diastereoselectivities when heated to 70 - 130 degrees C, under 10 kbar pressure. The reaction rates are at]east as high or higher than those of analogously tethered methylenecyclopropane-furan derivatives 15, 17, 20, in spite of the fact that the reactive double bond in bicyclopropylidene is tetrasubstituted and not activated by any electron withdrawing group. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0040-4020(96)00720-x