[5,15-bis(pentafluorophenyl)porphyrinato]zinc(II) | 205177-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [5,15-bis(pentafluorophenyl)porphyrinato]zinc(II)
• CAS: 205177-67-9
• 化学式: C₃₂H₁₀F₁₀N₄Zn
• 分子量: 705.832
• InChiKey: GWZQHRKPRJPGKZ-SJXPPYIZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.64
• 重原子数：
  47.0
• 可旋转键数：
  2.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.98
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  [5,15-bis(pentafluorophenyl)porphyrinato]zinc(II) 以 苯甲腈 为溶剂， 以11.6%的产率得到[5,15-bis(pentafluorophenyl)porphyrinato]zinc(II) dimer
  参考文献：
  名称：

  One-pot electrochemical formation of meso,meso-linked porphyrin arrays

  摘要：

  以铂网为工作电极，在苯甲腈中对[5,15-双(3,5-二叔丁基苯基)卟啉]锌(II) 1、[5,15-双(4-甲氧基羰基苯基)卟啉]锌(II)、[5,15-双(五氟苯基)卟啉]锌(II)或[10-溴-5、以铂网为工作电极，在苯甲腈中进行[10-溴-5,15-二苯基卟啉]锌（II）、[5,15-双（五氟苯基）卟啉]锌（II）或[10-溴-5,15-二苯基卟啉]锌（II）的反应，可以分离出相应的中链、中链低聚物卟啉阵列，其中 1.

  DOI：

  10.1039/a707653c

文献信息

• Metal Coordination-Directed Hydroxylation of Steroids with a Novel Artificial P-450 Catalyst
  作者：Zhenglai Fang、Ronald Breslow

  DOI：10.1021/ol052589i

  日期：2006.1.1

  Relative to a previous catalyst in which the manganese-porphyrin had four 2,2'-bipyridyl groups, the new catalyst, in the presence of Cu(2+) ions as coordinating linkers, catalyzes the oxidation of a steroid substrate with much better regioselectivity and higher turnover numbers.

  [结构：见正文]合成了一种新型催化剂，其中锰-卟啉单元在其四个内消旋位置上以反式连接到两个2,2'-联吡啶基和两个五氟苯基上。相对于以前的锰卟啉具有四个2,2'-联吡啶基的催化剂，该新催化剂在存在Cu（2+）离子作为配位连接体的情况下，催化甾体底物的氧化，具有更高的区域选择性和更高的营业额数字。
• Palladium-Catalyzed Cross-Coupling Reactions of Brominated Porphyrins with Functionalized Organomagnesium Reagents: Direct Preparation of Functional-Group-Bearing Free Base Porphyrins
  作者：Toshikatsu Takanami、Noriaki Sugita、Ikumi Tsuchiya

  DOI：10.3987/com-15-s(t)20

  日期：——

  The direct preparation of free-base porphyrins possessing reactive functional groups such as esters, halides, amide, nitriles, and acetals is described. This method relies on a simple one-pot procedure that involves sequential palladium-catalyzed cross-coupling of brominated free-base porphyrins with functionalized aryl and alkenylmagnesium reagents, which are readily prepared by iodine magnesium exchange of the corresponding organic iodides with the turbo Grignard reagent i-PrMgCl center dot LiCl, followed by demetallation of the resulting magnesium porphyrins under very mild conditions involving either a 1.2 M aqueous methanol solution of HCl or a 0.1 M methanol solution of citric acid at ambient temperature.
• Synthesis of phenylethyne-linked porphyrin dyads
  作者：Kin-ya Tomizaki、Andrey B Lysenko、Masahiko Taniguchi、Jonathan S Lindsey

  DOI：10.1016/j.tet.2004.01.003

  日期：2004.2

  Four new porphyrin dyads have been prepared for studies in artificial photosynthesis. The two porphyrins are joined at the meso positions via a phenylethyne linker and are present in zinc/zinc or zinc/free base metalation states. The porphyrin bearing the ethynyl unit incorporates zero, one, or two pentafluorophenyl groups at non-linking meso positions for tuning the porphyrin redox potentials. The synthetic approach entailed Pd-mediated coupling of porphyrin building blocks that bear a single ethynylphenyl or bromo/iodo substituent. (C) 2004 Elsevier Ltd. All rights reserved.