[Cu(triphenylstibine)(1,3-thiazolidine-2-thione)2Cl] | 263237-09-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Cu(triphenylstibine)(1,3-thiazolidine-2-thione)2Cl]
• 英文别名: [Cu(SbPh3)(tzdtH)2Cl]；chlorocopper;1,3-thiazolidine-2-thione;triphenylstibane
• CAS: 263237-09-8
• 化学式: C₂₄H₂₅ClCuN₂S₄Sb
• 分子量: 690.489
• InChiKey: QLCCVNCJQAXLOH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-巯基噻唑啉 、 chlorotris(triphenylstibine)copper(I) 以 苯 为溶剂， 以65.4%的产率得到[Cu(triphenylstibine)(1,3-thiazolidine-2-thione)2Cl]
  参考文献：
  名称：

  Synthesis and Characterization of Mixed- Ligand Complexes of Cu(I) Containing Halides, Triphenylstibine and Triphenylbismuthine, N,N-Dimethyl-N′-Phenylthiourea (Dmpth), N,N-Dibutyl-N′-Phenylthiourea (dbptH) and 1,3-thiazolidine-2-thione (tzdtH)

  摘要：

  The triphenylstibine and bismuthine complexes [Cu(EPh3)(LH)(2)X] (LH = N,N-dimethyl-N'-phenylthiourea) (dmptH), N,N-dibutyl-N'-phenylthiourea (dbptH) or 1,3-thiazolidine-2-thione (tzdtH); E = Sb or Bi; X = Cl, Br or I have been prepared and characterized on the basis of analytical, IR. electronic (UV-Vis), H-1 and C-13 NMR, FAB mass and conductivity measurements. In all cases there is a distorted tetrahedral environment around Cu(I) and the ligand (LH) binds through the thione sulphur atom to copper(I). This is confirmed by FTIR spectra of the complexes. The complexes show v(Cu-Sb) in the range 180-195 cm(-1).

  DOI：

  10.1080/00945710009351760