bis(4,4'-bipyridine-κN)bis(hydrogenphthtalato)-κ2O,O';κO-zinc(II) | 814919-87-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: bis(4,4'-bipyridine-κN)bis(hydrogenphthtalato)-κ2O,O';κO-zinc(II)
• CAS: 814919-87-4
• 化学式: C₃₆H₂₆N₄O₈Zn
• 分子量: 708.014
• InChiKey: BRDPVDTWWQQNTB-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 zinc(II) sulfate heptahydrate 、 邻苯二甲酸 以56%的产率得到bis(4,4'-bipyridine-κN)bis(hydrogenphthtalato)-κ2O,O';κO-zinc(II)
  参考文献：
  名称：

  Bis(4,4′-bipyridine-κN)bis(hydrogen phthalato)-κ²O,O′;κO-zinc(II)

  摘要：

  The title compound, [Zn(C8H5O4)(2)(C10H8N2)(2)], was obtained by the hydrothermal reaction of ZnSO4.7H(2)O with phthalic acid (H(2)pht) and 4,40-bipyridine (4,4'-bipy). Crystallographic analysis shows that it has a one-dimensional double-chain structure via hydrogen-bonding interactions. Each Zn-II atom, adopting a distorted tetrahedral geometry, is coordinated by two N atoms from two 4,4'-bipy ligands, with Zn-N distances of 2.054 (4) and 2.104 (4) Angstrom, and by two O atoms from symmetry-related Hpht(-) ligands, with Zn-O distances of 1.921 (4) and 2.019 (4) Angstrom.

  DOI：

  10.1107/s0108270104017184