[Au(PPh3)(tetrahydrothiophene)]ClO4 | 132461-17-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Au(PPh3)(tetrahydrothiophene)]ClO4
• 英文别名: {Au(tetrahydrothiophene)(triphenylphosphine)}(ClO4)；[Au(tetrahydrothiophene)(PPh3)]ClO4；gold(1+);thiolane;triphenylphosphane;perchlorate
• CAS: 132461-17-7
• 化学式: C₂₂H₂₃AuPS*ClO₄
• 分子量: 646.881
• InChiKey: SVQDDNBKEJJYCH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Au(PPh3)(tetrahydrothiophene)]ClO4 在 Na₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 生成 {Au(I)(1,3-thiazolidine-2-thionate)(triphenylphosphine)}
  参考文献：
  名称：

  Uson, Rafael; Laguna, Antonio; Laguna, Mariano, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：
• 作为产物：
  描述：

  三苯基膦氯金 、 Ag(tht)ClO₄ 以 二氯甲烷 为溶剂， 生成 [Au(PPh3)(tetrahydrothiophene)]ClO4
  参考文献：
  名称：

  Uson, Rafael; Laguna, Antonio; Laguna, Mariano, Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：

文献信息

• Synthesis and structural characterization of polynuclear complexes containing the eight-electron donor bis(diphenylphosphino)methanediide ligand
  作者：Eduardo J. Fernández、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、José M. López-de-Luzuriaga

  DOI：10.1039/dt9920003365

  日期：——

  various gold(I) or silver(I) compounds possessing a labile ligand such as tetrahydrothiophene or perchlorate to give [AuR2(Ph2P)2CH(ML)}]ClO4(ML = AuPPh3, AuCH2PPh3 or AgPPh3). Treatment of these derivatives with [Au(acac)(PPh3)] or [N(PPh3)2][Au(acac)Cl](acac = acetylacetonate) leads to [AuR2(Ph2P)2C(AuPPh3)(ML)}]ClO4 or [AuR2(Ph2P)2C(AuPPh3)(AuCl)}], in which the doubly deprotonated bis(diphen

  化合物[AuR 2 （Ph 2 P）2 CH}]（R = C 6 H 5）与各种具有不稳定配体（例如四氢噻吩或高氯酸盐）的金（I）或银（I）化合物反应生成[AuR 2 （Ph 2 P）2 CH（ML）}] ClO 4（ML = AuPPh 3，AuCH 2 PPh 3或AgPPh 3）。用[Au（acac）（PPh 3）]或[N（PPh 3）2 ] [Au（acac）Cl]（acac =乙酰丙酮酸）处理这些衍生物会产生[AuR 2 （Ph2 P） 2 C（AuPPh 3）（ML）}] ClO 4或[AuR 2 （Ph 2 P） 2 C（AuPPh 3）（AuCl）}]，其中双去质子化的双（二苯基膦基）甲烷二酰亚胺配体为八电子供体。化合物[AuR 2 （Ph 2 P） 2 C（AuPPh 3） 2 }] ClO 4也可以通过[AuR 2 （Ph 2 P） 2 CH 2 }] ClO
• Two-, three- and four-co-ordinate gold(I) complexes of 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane
  作者：Olga Crespo、M. Concepci�n Gimeno、Antonio Laguna、Peter G. Jones

  DOI：10.1039/dt9920001601

  日期：——

  ligand, three-co-ordinate (L = SPPh3, AsPh3, or C5H4NSH) or four-co-ordinate complexes [L = 1,10-phenanthroline or (PPh2)2C2B10H10] can be synthesised. The bis-chelated gold(I) phosphine complex [Au(PPh2)2C2B10H10}2]ClO4 has been isolated. The crystal structure of [Au(PPh3)(PPh2)2C2B10H10}]ClO4·CH2Cl2 has been established by X-ray crystallography: monoclinic space group P21/n, a= 11.760(3), b= 20

  用金（I）络合物[AuX（tht）]（tht =四氢噻吩，X = Cl或C 6 F 5）处理（PPh 2）2 C 2 B 10 H 10产生两个坐标的[（AuX）2 （PPh 2）2 C 2 B 10 H 10 }]或三坐标[AuX （PPh 2）2 C 2 B 10 H 10 }]物种。从[Au（tht）L] ClO 4（L = tht，PR 3（或叶立德）与二膦反应。将tht替换为[Au（tht）（PPh 2）2 C 2 B 10 H 10 }] ClO 4得到[AuL （PPh 2）2 C 2 B 10 H 10 }] ClO 4其中，取决于配体，三坐标（L = SPPh 3，ASPh 3或C 5 H 4 NSH）或四坐标复合物[L = 1,10-菲咯啉或（PPh 2）2 C 2 B 10 H 10]可以合成。已分离出双螯合的金（I）膦复合物[Au （PPh 2）2 C 2
• Different coordination modes of the 1,1,1-tris(diphenylphosphinomethyl) ethane ligand in gold(I) and gold(III) complexes
  作者：Eduardo J Fernández、M Concepción Gimeno、Antonio Laguna、Mariano Laguna、JoséM López-de-Luzuriaga、Elena Olmos

  DOI：10.1016/0022-328x(95)06025-r

  日期：1996.5

  [Au(C6F5)}2(μ−η2-tdppmeO)], [Au(C6F5)3(η1-tdppme)] or [Au(C6F5)2(η2-tdppme]Cl. The mononuclear derivatives further react with gold(I) or gold(III) species giving rise to di- or tri-nuclear complexes which contain the triphosphine acting as a μ3−η3, μ−η3or η2 ligand.

  具有三齿配体（PPh 2 CH 2）3 CCH 3（tdppme）的五氟苯基单核或多核金（I）和/或金（III）配合物的合成以迄今未呈现的不同配位模式进行了描述。有金（I）或在不同摩尔比金（III）衍生物的游离的膦的反应，得到[的Au（C 6 ˚F 5）} 3（μ 3 - η 3 -tdppme）]，[的Au（C 6 ˚F 5）} 2（μ - η 2 -tdppmeO）]，[金（C 6 ˚F 5）3（η 1 -tdppme）]或[金（C 6 ˚F 5）2（η 2 -tdppme] CL上。单核衍生物与金进一步反应（I）或金（III）物质引起的二-或三-其含有triphosphine充当核络合物μ 3 - η 3，μ - η 3或η 2配体。
• Gold(I) Complexes with the <i>nido</i>-Diphosphino Ligand [7,8-(Ph₂P)₂-7,8-C₂B₉H₁₀]^-. Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh₂)₂C₂B₉H₁₀}(PPh₃)]·CH₂Cl₂ and [Au₂{(PPh₂)₂C₂B₉H₁₀}₂{(PPh₂)₂(CH₂)₃}]·3Me₂CO
  作者：Olga Crespo、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna

  DOI：10.1021/ic951204x

  日期：1996.1.1

  [Au(2)(PPh(2))(2)C(2)B(9)H(9)}(PPh(3))(2)] (8). The structure of complexes 1 and 7 have been established by X-ray diffraction. [Au(PPh(2))(2)C(2)B(9)H(10)}(PPh(3))] (1) (dichloromethane solvate) crystallizes in the monoclinic space group P2(1)/c, with a = 17.326(3) Å, b = 20.688(3) Å, c = 13.442(2) Å, beta = 104.710(12) degrees, Z = 4, and T = -100 degrees C. [Au(2)(PPh(2))(2)C(2)B(9)H(10)}(2)(&mgr;-dppp)]

  [AuCl（PR（3））]与[1,2-（Ph（2）P）（2）-1,2-C（2）B（10）H（10）]在回流的乙醇中的反应进行与部分降解（去除碳原子附近的硼原子）的closo物种得到[Au （PPh（2））（2）C（2）B（9）H（10）}（PR（3）） ] [PR（3）= PPh（3）（1），PPh（2）Me（2），PPh（2）（4-Me-C（6）H（4））（3），P（4- Me-C（6）H（4））（3）（4），P（4-OMe-C（6）H（4））（3）（5）]。同样，用[1,2-（Ph（2）P）（2）-1,2-C（2）B（10）处理[Au（2）Cl（2）（＆mgr; -PP）] H（10）]在相同条件下导致络合物[Au（2）（PPh（2））（2）C（2）B（9）H（10）}（2）（＆mgr; -PP） ] [PP ＝ dppe ＝ 1，2-双（二苯基膦基）乙烷（6），dppp ＝ 1，
• Synthesis of heterometallic species with (Ph₂P)₃CH or (Ph₂P)₃C^–. Crystal structures of [Mo(CO)₄{(PPh₂)₂CHPPh₂AuCl}], [Mo(CO)₄{(PPh₂)₂CHPPh₂Au(C₆F₅)}] and [NBu]₄[Mo(CO)₄{(PPh₂)₂CPPh₂Au(C₆F₅)}]
  作者：Eduardo J. Fernández、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、Elena Olmos

  DOI：10.1039/dt9940002891

  日期：——

  Treatment of [M(CO)4(PPh2)2CHPPh2}] (M = Cr a, Mo b or W c) with 1 equivalent of [AuX(tht)] or [Au(tht)(PPh3)]ClO4 (tht = tetrahydrothiophene) afforded the neutral binuclear complexes [M(CO)4(PPh2)2CHPPhAuX}] (X = Cl la-lc or C6F5 2a-2c), or the cationic derivatives [M(CO)4(PPh2)2CHPPh2Au(PPh3)}]ClO4 3a-3c. Complexes 2 and 3 are readily deprotonated by [NBu4] (acac] (acac = acetylacetonate) to give the tris(diphenylphosphino)methanide species [MBu4]-[M(CO)4(PPh2)2CPPh2Au(C6F5)}] 4a-4c and [M(CO)4(PPh2)2CPPh2Au(PPh3)}] (5a-5c). Trinuclear compounds of the type [NBu4][M(CO)4[(PPh2)2CPPh2]}2Au] 6a-6c were obtained by reaction of [M(CO)4(PPh2)2CHPPh2}] with [NBu4][Au(acac)2] in the ratio 2:1. Single-crystal structure determinations were performed for compounds lb, 2b and 4b. In the neutral complexes lb and 2b the atoms C(2) (carbonyl), Mo, P(1) (co-ordinated to Au) and Au are essentially coplanar; the principal structural differences between the neutral and anionic (4b) complexes are the shorter P-C bonds and a rotation about the C-P(l) bond in the latter complex.