Phenyldiethylphosphinit | 25781-03-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyldiethylphosphinit
• 英文别名: Diethyl(phenoxy)phosphane
• CAS: 25781-03-7
• 化学式: C₁₀H₁₅OP
• 分子量: 182.202
• InChiKey: HDIXLMTYOWVGSS-UHFFFAOYSA-N

物化性质

• 沸点：
  232.9±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Phenyldiethylphosphinit 在 selenium 作用下， 生成 O-Phenyl-diethylphosphinoselenoat
  参考文献：
  名称：

  Bayandina,E.V.; Nuretdinov,I.A., Journal of general chemistry of the USSR, 1976, vol. 46, p. 285 - 287

  摘要：

  DOI：

文献信息

• Selective Hydrogenation Catalyst and Methods of Making and Using Same
  申请人：Cheung Tin-Tack Peter

  公开号：US20100228065A1

  公开（公告）日：2010-09-09

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons. A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a palladium supported composition, contacting the palladium supported composition with an organophosphorus compound to form a catalyst precursor, and reducing the catalyst precursor to form the catalyst. A method of selectively hydrogenating highly unsaturated hydrocarbons to an unsaturated hydrocarbon enriched composition comprising contacting a supported catalyst comprising palladium and an organophosphorous compound with a feed comprising highly unsaturated hydrocarbon under conditions suitable for hydrogenating at least a portion of the highly unsaturated hydrocarbon feed to form the unsaturated hydrocarbon enriched composition.

  一种包括支持的氢化催化剂的组合物，其中氢化催化剂包括钯和有机磷化合物，支持的氢化催化剂能够选择性地将高度不饱和烃氢化为不饱和烃。一种制备选择性氢化催化剂的方法，包括将支持物与含钯化合物接触以形成支持的钯组合物，将支持的钯组合物与有机磷化合物接触以形成催化剂前体，并还原催化剂前体以形成催化剂。一种将高度不饱和烃选择性氢化为富含不饱和烃的组合物的方法，包括将包括钯和有机磷化合物的支持催化剂与含高度不饱和烃的进料接触，在适宜的氢化条件下至少部分氢化高度不饱和烃进料以形成富含不饱和烃的组合物。
• Mononuclear cobalt carbonyls containing monodentate thiolate or xanthate groups. The structures of PhSCo(CO)2(PPh2OMe)2 and MeOCS2Co(CO)2(PPh2iBu)2
  作者：Sándor Vastag、László Markó、Arnold L. Rheingold

  DOI：10.1016/0022-328x(90)80241-q

  日期：1990.11

  Complexes of the type PhSCo(CO)2L2 (1; L = phosphine or phosphite) and the complex MeOCS2Co(CO)2(PPh2iBu)2 (5) have been prepared from CoCl2 · 6H2O, CO, the appropriate phosphine or phosphite, and PhSH + NaOMe or MeOCS2K, respectively. The crystal structures of 1a (L = PPh2OMe) and 5 · MeCN have been determined. These compounds are the first structurally characterized cobalt carbonyl complexes containing

  由CoCl 2 ·6H 2 O制备了PhSCo（CO）2 L 2（1； L =膦或亚磷酸酯）类型的配合物和MeOCS 2 Co（CO）2（PPh 2 i Bu）2（5）的配合物。，CO，适当的膦或亚磷酸酯，和加入PhSH +的NaOMe或MeOCS 2 K，分别。已确定1a（L = PPh 2 OMe）和5 ·MeCN的晶体结构。这些化合物是第一个具有单齿硫醇盐或黄药酸酯基团的结构特征化的羰基钴复合物。
• Process for preparing N-tritylimidazole compounds
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0010565A1

  公开（公告）日：1980-05-14

  The invention relates to a novel process for preparing N-tritylimidazole compounds of the formula: by the reaction between a tritylcarbino derivative of the formula: an an imidazole derivative of the formula: characterized in that the reaction is effected in the presence of a phosphorus compound of the formula:

  本发明涉及一种制备式 N-三苯甲基咪唑化合物的新工艺，该工艺通过式 N-三苯甲基氨基衍生物与式 N-三苯甲基咪唑衍生物之间的反应制备，其特征在于该反应是在式 N-三苯甲基氨基衍生物与式 N-三苯甲基咪唑衍生物之间的反应中进行的：
• SELECTIVE HYDROGENATION CATALYST AND METHODS OF MAKING AND USING SAME
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP3144064A2

  公开（公告）日：2017-03-22

  A composition comprising a supported hydrogenation catalyst comprising palladium and an organophosphorous compound, the supported hydrogenation catalyst being capable of selectively hydrogenating highly unsaturated hydrocarbons to unsaturated hydrocarbons.

  一种由钯和有机磷化合物组成的载体加氢催化剂组成的组合物，该载体加氢催化剂能选择性地将高度不饱和烃加氢为不饱和烃。
• LANTHANOID-CONTAINING INORGANIC MATERIAL MICROPARTICLES, WAVELENGTH-CONVERTING INK, COATED ARTICLE, AND DETERMINATION APPARATUS
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP3409748A1

  公开（公告）日：2018-12-05

  The present invention aims to provide a lanthanoid-containing inorganic material fine particle that enables achievement of high luminous efficiency with less energy outflow upon conversion of the wavelength of light to a shorter wavelength. The present invention can also provide a wavelength conversion ink capable of maintaining a high emission intensity at the time of wavelength conversion for a long period of time, having high water repellency, and capable of forming a printing pattern excellent in retention properties, a coated article produced using the wavelength conversion ink, and a determination apparatus. The present invention relates to a lanthanoid-containing inorganic material fine particle having a function of converting a wavelength of light to a shorter wavelength, the lanthanoid-containing inorganic material fine particle including: a core particle; and a shell layer, the core particle containing a lanthanoid having a light-absorbing function and a lanthanoid having a light-emitting function, the shell layer including at least an outer shell containing a rare earth element, the total amount of the lanthanoid having a light-absorbing function and the lanthanoid having a light-emitting function in the outer shell being 2 mol% or less based on the amount of the rare earth element contained in the outer shell, the outer shell having a thickness of 2 to 20 nm, the core particle and the shell layer having no interface at a contact face to form a continuous body.

  本发明的目的是提供一种含有类镧系元素的无机材料微粒，该微粒能够在将光的波长转换为较短波长时以较少的能量流出实现较高的发光效率。本发明还可以提供一种波长转换油墨，该油墨能够在波长转换时长时间保持高发射强度，具有高防水性，并且能够形成保持性能优异的印刷图案，还可以提供一种使用该波长转换油墨生产的涂布制品和一种测定装置。本发明涉及一种具有将光波长转换为较短波长功能的含类镧系元素的无机材料微粒，该含类镧系元素的无机材料微粒包括：核心颗粒核心颗粒含有具有光吸收功能的类镧系元素和具有发光功能的类镧系元素，外壳层至少包括含有稀土元素的外壳、外壳中具有光吸收功能的类镧系元素和具有发光功能的类镧系元素的总量为 2 摩尔%或更少（基于外壳中所含稀土元素的量），外壳的厚度为 2 至 20 纳米，核心颗粒和外壳层在接触面处没有界面，形成一个连续体。