(1R,2R,3R,4S,5S)-1-hydroxymethyl-2,3-dibenzyloxy-4,5-dihydroxycycloheptane | 524722-80-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1R,2R,3R,4S,5S)-1-hydroxymethyl-2,3-dibenzyloxy-4,5-dihydroxycycloheptane
• CAS: 524722-80-3
• 化学式: C₂₂H₂₈O₅
• 分子量: 372.461
• InChiKey: ZMURISQDCVBQLY-CDJZJNNCSA-N

反应信息

• 作为反应物：
  描述：

  (1R,2R,3R,4S,5S)-1-hydroxymethyl-2,3-dibenzyloxy-4,5-dihydroxycycloheptane 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 5.0h， 以92%的产率得到(1S,2S,3S,4R,5R)-5-Hydroxymethyl-cycloheptane-1,2,3,4-tetraol
  参考文献：
  名称：

  Cycloheptanic sugar mimetics, bridging the gap in the homologous series of carbocyclic analogues

  摘要：

  The cycloheptanic analogues Of alpha-D-glucopyranose and P-D-mannopyranose have been synthesized. These two members of a new class of carbocyclic sugar mimetics are filling the gap between already existing cyclohexanic and cyclooctanic classes of sugar mimetics. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)01402-3
• 作为产物：
  描述：

  (1R,2R,3S,4S,5S)-1-hydroxymethyl-2,3-dibenzyloxy-4,5-O-isopropylidenecycloheptane 在 三氟乙酸 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 24.0h， 以82%的产率得到(1R,2R,3R,4S,5S)-1-hydroxymethyl-2,3-dibenzyloxy-4,5-dihydroxycycloheptane
  参考文献：
  名称：

  Cycloheptanic sugar mimetics, bridging the gap in the homologous series of carbocyclic analogues

  摘要：

  The cycloheptanic analogues Of alpha-D-glucopyranose and P-D-mannopyranose have been synthesized. These two members of a new class of carbocyclic sugar mimetics are filling the gap between already existing cyclohexanic and cyclooctanic classes of sugar mimetics. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)01402-3