3-甲基十一腈 | 85351-07-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 3-甲基十一腈
• 中文别名: 甜橙腈
• 英文名称: 3-methyldodecanenitrile
• 英文别名: 3-Methyldodecanonitrile
• CAS: 85351-07-1
• 化学式: C₁₃H₂₅N
• mdl: MFCD00169832
• 分子量: 195.348
• InChiKey: ZKCZXPOYIUVRIV-UHFFFAOYSA-N

物化性质

• LogP：
  5.115 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.923
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-十一酮 、 氰甲基磷酸二乙酯 在 lithium methanolate 、 氨 、 lithium perchlorate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 以82%的产率得到3-甲基十一腈
  参考文献：
  名称：

  氨的电化学串联烯烃和加氢反应

  摘要：

  使用氨作为电子和质子供体实现了电化学 Horner-Wadsworth-Emmons/氢化串联反应。该反应可以直接由醛或酮得到双碳延伸的酯和腈。该反应可以在催化量的碱或什至没有碱的情况下进行。氨为该串联反应提供电子和质子，并使 α,β-不饱和 HWE 中间体的无催化剂氢化成为可能。报告了 40 多个例子，并且可以容忍包括杂环和羟基在内的官能团。

  DOI：

  10.1021/acs.joc.1c01024

文献信息

• PERFUME COMPOSITIONS
  申请人：Bradshaw David Jonathan

  公开号：US20110182832A1

  公开（公告）日：2011-07-28

  Perfume ingredients have been investigated and classified for their effectiveness in detaching biofilms from surfaces. Based on this classification, perfume compositions that are effective in assisting biofilm detachment can be formulated, whilst also allowing a degree of freedom in formulation that permits consideration of the hedonic properties of the composition. The compositions can be used in a wide range of perfumed consumer products, such as personal, domestic and industrial products, e.g. hard surface cleaning products, dental care products, and deodorant products.

  香水成分已经被研究和分类，以确定它们在从表面去除生物膜方面的有效性。根据这种分类，可以制定有效辅助生物膜去除的香水配方，同时在配方上具有一定的自由度，以考虑配方的感官特性。这些配方可以用于各种香水消费品，如个人、家用和工业产品，例如硬表面清洁产品、口腔护理产品和除臭产品。
• FRAGRANT CONSUMER PRODUCTS COMPRISING OXIDIZING AGENTS
  申请人：Schmiedel Peter

  公开号：US20090081755A1

  公开（公告）日：2009-03-26

  Fragrant consumer products comprising oxidizing agents are described, which may be, for example, detergents or cleaners or, for example, also cosmetics. These consumer products comprise certain minimum amounts of fragrances of certain classes of substances. They are characterized by very good (storage) stability, both with regard to the fragrance of the product, and also with regard to the potency of the oxidizing agent.

  本发明涉及含有氧化剂的芳香消费品，例如洗涤剂、清洁剂或化妆品等。这些消费品包含特定类别物质的最低浓度的香料。它们的特点是非常好的（储存）稳定性，不仅针对产品的香味，也针对氧化剂的效力。
• Ketones useful as precursors for organoleptic compounds
  申请人：Givaudan Roure (International) S.A.

  公开号：EP0983990A2

  公开（公告）日：2000-03-08

  The ketones of the formula I are useful for the delivery of organoleptic compounds, especially for flavours, fragrances and masking agents and antimicrobial compounds.

  式 I 中的酮类化合物可用于传递感官化合物，特别是香精、香料、掩蔽剂和抗菌化合物。
• A FRAGRANCE-DELIVERY COMPOSITION COMPRISING PERSULFATE ION-CROSSLINKED POLYVINYL ALCOHOL MICROCAPSULES AND METHOD OF USE THEREOF
  申请人：APPVION, INC.

  公开号：EP2907568A1

  公开（公告）日：2015-08-19

  An aqueous composition is provided having a pH of from about 2.0 to about 5.7 to about 12.8 and comprising boron or persulfate ion-crosslinked polyvinyl alcohol microcapsules. A method of delivering a fragrance to a substrate is further provided comprising applying to the substrate an aqueous composition comprised of fragrance-containing, boron or persulfate ion-crosslinked, polyvinyl alcohol microcapsules, as well as a method of cleaning a substrate comprising applying to the substrate an aqueous composition comprised of fragrance-containing, boron or persulfate ion-crosslinked, polyvinyl alcohol microcapsules together with at least one cleaning component.

  本发明提供了一种水性组合物，其 pH 值为约 2.0 至约 5.7 至约 12.8，并包含硼或过硫酸根离子交联的聚乙烯醇微胶囊。本发明还提供了一种向基底输送香料的方法，包括向基底施用由含香、硼或过硫酸根离子交联的聚乙烯醇微胶囊组成的水性组合物，以及一种清洁基底的方法，包括向基底施用由含香、硼或过硫酸根离子交联的聚乙烯醇微胶囊组成的水性组合物和至少一种清洁成分。
• Microcapsules
  申请人：Givaudan, S.A.

  公开号：US10537868B2

  公开（公告）日：2020-01-21

  Encapsulated perfume composition comprising at least one aminoplast core-shell microcapsule dispersed in a suspending medium, the microcapsule comprising a perfume-containing core encapsulated in a shell, said shell comprising a network of cross-linked aminoplast resin, wherein 75-100% of the resin comprises 50-90%, preferably from 60-85%, of a terpolymer and from 10-50%, preferably from 10-25%, of a polymeric stabilizer; the terpolymer comprising: (a) from 20-35 wt %, preferably 22-30% by weight of moieties derived from at least one triamine, (b) from 30-60 wt %, preferably 40-55% by weight of moieties derived from at least one diamine, (c) from 20-35 wt %, preferably 22-30% by weight of moieties derived from the group consisting of alkylene and alkylenoxy moieties having 1 to 6 methylene units, preferably 1 to 4 methylene units and most preferably 1 methylene unit. The encapsulated perfume composition is useful for the storage and dissemination of fragrance in various products, such as laundry products and fabric care products.

  封装香水组合物，包括至少一个分散在悬浮介质中的氨基树脂芯壳微胶囊，所述微胶囊包括封装在外壳中的含香水的芯，所述外壳包括交联氨基树脂网络，其中75-100%的树脂包括50-90%，优选60-85%的三元共聚物和10-50%，优选10-25%的聚合物稳定剂；所述三元共聚物包括： (a) 20-35%，最好是 22-30%（按重量计）由至少一种三胺衍生的分子、 (b) 30-60%（按重量计），最好是 40-55%（按重量计）衍生自至少一种二胺的分子、 (c) 20-35%，优选 22-30%（按重量计）来自具有 1 至 6 个亚甲基单元，优选 1 至 4 个亚甲基单元，最优选 1 个亚甲基单元的亚烷基和亚烷氧基分子组成的组的分子。 封装的香水组合物适用于在各种产品（如洗衣产品和织物护理产品）中储存和传播香味。