[Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate) | 914102-94-6

• 分子结构分类: 有机化合物
• 英文名称: [Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate)
• CAS: 914102-94-6
• 化学式: C₂₈H₃₈N₈NiO₂Ru*ClO₄
• 分子量: 777.873
• InChiKey: JNDRNKUZGMQMEB-HXKMMAKISA-K

反应信息

• 作为产物：
  描述：

  (1,4,8,11-tetraazacyclotetradecane)nickel(II) perchlorate 、 sodium[ruthenium(III)(ethylenebis(salicylimine))(cyanide)2]*1.5(water) 以 水 、 乙腈 为溶剂， 以72%的产率得到[Ru(III)(ethylenebis(salicylimine))(cyanide)2][Ni(II)(1,4,8,11-tetraazacyclotetradecane)](perchlorate)
  参考文献：
  名称：

  Magnetic and structural properties of a cyano-bridged 1D ruthenium(III)–nickel(II) coordination polymer

  摘要：

  Reaction of [Ni(cyclam)](ClO4)(2) (cyclam = 1,4,8,1 1-tetraazacyclotetradecane) with Na[Ru(salen)(CN)(2)] (2) (salen = ethylenebis(salicylimine)) generated the ID coordination polymer [Ru(III)(salen)(CN)(2)][Ni(II)(cyclam)](ClO4) (1). X-ray diffraction studies of 1 revealed a structure consisting of alternating Ni(II) and Ru(III) ions bridged by cyanide ligands. The cyano C-terminus remained bound to the Ru(III) center while the perchlorate anion induced a deviation from linearity along the Ru-CN-Ni axis. Structural characterization of 2 disclosed a 2D framework where the sodium counterions bridge between [Ru(salen)(CN)(2)] units. Magnetic measurements of I indicate ferromagnetic coupling between Ni(II) and Ru(III) with no long-range magnetic order above 3 K. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.024