1-ethyl-1-propenylthiobenzene | 99965-74-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1-ethyl-1-propenylthiobenzene
• 英文别名: [(Z)-pent-2-en-3-yl]sulfanylbenzene
• CAS: 99965-74-9
• 化学式: C₁₁H₁₄S
• 分子量: 178.298
• InChiKey: IKPPVBCGCZILFZ-KMKOMSMNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-ethyl-1-propenylthiobenzene 、 chloroamine-T 以50%的产率得到
  参考文献：
  名称：

  KAKIMOTO M.; YAMAMOTO T.; OKAWAZA M., TETRAHEDRON LETT., 1979, NO 7, 623-624

  摘要：

  DOI：
• 作为产物：
  描述：

  α-chloropropyl phenyl sulfide 、 lithium α-carbanion of propionitrile 以60%的产率得到
  参考文献：
  名称：

  HARADA, TOSHIRO;KARASAWA, AKIO;OKU, AKIRA, J. ORG. CHEM., 1986, 51, N 6, 842-846

  摘要：

  DOI：

文献信息

• Regioselectivity of the Singlet Oxygen Ene Reaction (Schenck Reaction) with Vinylsilanes
  作者：Waldemar Adam、Markus J. Richter

  DOI：10.1021/jo00091a020

  日期：1994.6

  The ene reaction-of singlet oxygen and vinylsilanes 1 with various substitution patterns and double-bond geometry has been studied. beta-Silyl allylic hydroperoxides 2 were the major products of the photooxygenation, accompanied by smaller amounts of alpha,beta-unsaturated ketones 3. The latter derive from decomposition of the regioisomeric alpha-hydroperoxy silanes 4 by elimination of silanol. Regioselectivities up to 97:3 were observed for vinylsilanes with a methyl group geminal to the silyl group and with cyclic derivatives. Z-Configurated substrates showed lower regioselectivity and reactivity. Elongation of the carbon chain at the geminal position also increased the amount enone formed. These results are rationalized in terms of stereoelectronic effects imposed by the silyl group on the ring-opening of the perepoxide intermediate.
• TAKEDA, TAKESHI;TSUCHIDA, TOSHIO;NAKAGAWA, ICHIRO;OGAWA, SHINJI;FUJIWARA,+, TETRAHEDRON LETT., 1985, 26, N 43, 5313-5316
  作者：TAKEDA, TAKESHI、TSUCHIDA, TOSHIO、NAKAGAWA, ICHIRO、OGAWA, SHINJI、FUJIWARA,+

  DOI：——

  日期：——
• TAKEDA, TAKESHI;KANEKO, YUICHIRO;NAKAGAWA, HITOSHI;FUJIWARA, TOORU, CHEM. LETT.,(1987) N 10, 1963-1966
  作者：TAKEDA, TAKESHI、KANEKO, YUICHIRO、NAKAGAWA, HITOSHI、FUJIWARA, TOORU

  DOI：——

  日期：——
• TAKEDA TAKESHI; KANEKO YUICHIRO; FUJIWARA TOORU, TETRAHEDRON LETT., 27,(1986) N 26, 3029-3032
  作者：TAKEDA TAKESHI、 KANEKO YUICHIRO、 FUJIWARA TOORU

  DOI：——

  日期：——