Zn(5-amino-1,3-benzenedicarboxylate)*H₂O | 442518-94-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(5-amino-1,3-benzenedicarboxylate)*H₂O
• 英文别名: [Zn(5-aminoisophthalate)(H₂O)]；ZnAPA
• CAS: 442518-94-7
• 化学式: C₈H₅NO₄*H₂O*Zn
• 分子量: 262.537
• InChiKey: WNUSNEGCCQMVNX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.83
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  137.78
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 5-氨基间苯二甲酸 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 72.0h， 生成 Zn(5-amino-1,3-benzenedicarboxylate)*H₂O
  参考文献：
  名称：

  发光金属-有机骨架在紫外光照射下芳香胺的荧光检测和若丹明B的光催化降解

  摘要：

  对于安全问题和污染控制而言，痕量芳族胺的检测非常重要。战略上，两个多功能金属有机框架（MOF）[ZnL·H 2 O] n（1）和[CdL·H 2 O] n ·2 n H 2 O（2）（L = 5-氨基间苯二甲酸）选择用于检测芳香胺污染物的方法。荧光实验表明，两种MOF可以高灵敏度地选择性检测芳香胺。在给定的分析物中，对硝基苯胺（一种电子缺陷分析物）显着淬灭了1和2的荧光强度。相反，其他芳族胺在一定程度上增强了1和2的荧光强度。特别地，在相同的实验条件下，二苯胺比其他苯胺具有最明显的增强作用。此外，还通过紫外光诱导的罗丹明B（RhB）实验确定了两个MOF的光催化活性。所有结果表明，所研究的配合物既稳定又很好，既可以用作多相光催化剂，也可以用作芳族胺的可检测材料。

  DOI：

  10.1039/c4nj02356k

文献信息

• Porous Metal–Organic Frameworks with 5-Aminoisophthalic Acid as Platforms for Functional Applications about High Photodegradation Efficiency of Phenol
  作者：Ying Wang、Li-Jing Zhang、Rui Zhang、Yu Jin、Yang Wang、Yong-Heng Xing、Feng-Ying Bai、Li-Xian Sun

  DOI：10.1021/acs.cgd.7b01190

  日期：2017.12.6

  Four novel complexes, [CoL(H2O)] (1), [ZnL(H2O)] (2), [Ni(HL)2(H2O)2]·2H2O (3), and [CdL(H2O)]·H2O (4) (L = 5-aminoisophthalic acid), were successfully synthesized by the reaction of transition metal salts and 5-aminoisophthalic acid at hydrothermal conditions. The four complexes were characterized by element analysis, infrared spectra, UV–vis spectra, powder X-ray diffraction analysis, and thermogravimetric

  四种新型配合物，[CoL（H 2 O）]（1），[ZnL（H 2 O）]（2），[Ni（HL）2（H 2 O）2 ]·2H 2 O（3）和[CdL（H 2 O）]·H 2 O（4（L ＝ 5-氨基间苯二甲酸），是通过过渡金属盐与5-氨基间苯二甲酸在水热条件下反应而成功合成的。通过元素分析，红外光谱，紫外-可见光谱，粉末X射线衍射分析和热重分析对这四种配合物进行了表征。X射线单晶衍射分析表明，这四个络合物是3D网络结构，并包含尺寸为7.05至14.67Å的孔。此外，我们研究了这四种配合物在紫外线照射下对苯酚溶液的光降解能力。结果表明，四种配合物对苯酚溶液的降解能力不同。同时，我们发现退化过程符合伪二级动力学模型，即 降解速率由颗粒外过程（例如表面吸附）控制。此外，我们通过高效液相色谱法进一步证实，该配合物确实具有显着的降解苯酚的能力。
• An acid-base resistant Zn-based metal-organic framework as a luminescent sensor for mercury(II)
  作者：Junling Jiang、Yantong Lu、Jingwen Liu、Yunchun Zhou、Dian Zhao、Chunxia Li

  DOI：10.1016/j.jssc.2019.121153

  日期：2020.3

  A monocyclic organic ligand 5-aminoisophthalic acid (H2APA) with one amino and two carboxylic groups, has been employed to construct a stable Zn-based metal-organic framework, ZnAPA. It features a 3D supramolecular network containing the pores with a size of 8.2 Å and uncoordinated carboxylic oxygen atoms, exhibiting a pronounced fluorescence response (fast response, high sensitivity and selectivity)

  具有一个氨基和两个羧基的单环有机配体5-氨基间苯二甲酸（H 2 APA）已用于构建稳定的Zn基金属有机骨架ZnAPA。它具有一个3D超分子网络，该网络包含8.2Å大小的孔和未配位的羧基氧原子，与水溶液中的其他金属离子相比，对Hg 2+离子表现出明显的荧光响应（快速响应，高灵敏度和选择性）。还涉及可能的基于荧光的传感机制。重要的是，ZnAPA具有出色的耐酸碱稳定性，突出了其在实际应用中检测Hg 2+的潜在用途。
• From lamellar net to bilayered-lamella and to porous pillared-bilayer: reversible crystal-to-crystal transformation, CO₂adsorption, and fluorescence detection of Fe³⁺, Al³⁺, Cr³⁺, MnO₄⁻, and Cr₂O₇²⁻in water
  作者：Jia-Rong Zhang、Jey-Jau Lee、Chun-Hao Su、Meng-Jung Tsai、Chih-Yu Li、Jing-Yun Wu

  DOI：10.1039/d0dt02606a

  日期：——

  Layered coordination polymers of different network topologies have showed reversible structural transformations and fluorescence detection toward Fe³⁺, Al³⁺, Cr³⁺, MnO₄^–, and Cr₂O₇^2– in water.

  不同网络拓扑结构的分层配位聚合物在水中表现出可逆的结构转变和对Fe3 +、Al3 +、Cr3 +、MnO4-和Cr2O72-的荧光检测。
• Room temperature phosphorescence of Mn(<scp>ii</scp>) and Zn(<scp>ii</scp>) coordination polymers for photoelectron response applications
  作者：Xiao-Gang Yang、Zhi-Min Zhai、Xiao-Min Lu、Ying Zhao、Xin-Hong Chang、Lu-Fang Ma

  DOI：10.1039/c9dt02178g

  日期：——

  Room temperature phosphorescence of Mn(II) and Zn(II) based coordination polymers (Mn-CP and Zn-CP) with a different mechanism was confirmed by experiments and theory calculations. The Mn-CP exhibits high photoelectron response performance while Zn-CP can generate frequency tunable alternating current when the period of on–off illumination is changed.

  通过实验和理论计算证实了Mn（II）和Zn（II）基配位聚合物（Mn-CP和Zn-CP）具有不同机理的室温磷光。Mn-CP表现出高的光电子响应性能，而Zn-CP可以通过改变开关照明的周期来产生频率可调的交流电。
• Hydrothermal Synthesis, Structures, and Magnetic Properties of Three Novel 5-Aminoisophthalic Acid Ligand Bridged Transition Metal Cation Polymers
  作者：Chuan-De Wu、Can-Zhong Lu、Wen-Bin Yang、Hong-Hui Zhuang、Jin-Shun Huang

  DOI：10.1021/ic011182g

  日期：2002.6.1

  Three novel 5-aminoisophthalic acid (AIP) bridged polymers [Co(C8NH5O4)(H2O)](n) (1), [Ni(C8NH5O4)(H2O)](n) (2), and [Zn(C8NH5O4)(H2O)](n) (3) were synthesized by hydrothermal reactions and characterized by IR, Raman, elemental analysis, ESR, and magnetic measurements. X-ray single-crystal analyses were carried out for [Co(C8NH5O4)(H2O)](n) (1), which crystallizes in the triclinic system, space group P (1) over bar, with a = 6.477(1) Angstrom, b = 7.130(1) Angstrom, c = 9.826(2) Angstrom, alpha = 108.9(1)degrees, beta = 93.97(3)degrees gamma = 98.82(3)degrees, and Z = 2; for [Ni(C8NH5O4)(H2O)(2)](n) (2), in the triclinic system, space group P (1) over bar, a = 6.425(1) Angstrom, b = 8.115(2) Angstrom, c = 10.146(2) Angstrom, alpha = 113.09(3)degrees, beta = 99.64(3)degrees gamma = 98.90(3)degrees, and Z = 2; and for [Zn(C8NH5O4)(H2O)](n) (3), in the monoclinic system, space group P2(1)ln, a 9.044(1) Angstrom, b = 8.264(1) Angstrom, c = 11.646(1) Angstrom, beta = 100.77(1)degrees, and Z = 4. The single X-ray diffraction studies reveal that 1 consists of an infinite honeycomb layer formed by four crystallographically independent motifs packed alternatively together; 2 consists of an infinite neutral railroad-like linear polymer, and 3 consists of infinite layers of alternating four-coordinated Zn(II) cations and AIP ligands. Finally, they are all packed into beautiful threedimensional frameworks through complicated hydrogen bonding. Antiferromagnetic and ferromagnetic behaviors were observed for 1 and 2 from the magnetic measurements.