bis[2-(2-pyridylmethyleneamino)-N-tosylanilinato]cobalt(II) | 114610-82-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[2-(2-pyridylmethyleneamino)-N-tosylanilinato]cobalt(II)
• CAS: 114610-82-1
• 化学式: C₃₈H₃₂CoN₆O₄S₂
• 分子量: 759.835
• InChiKey: SRJUAJKDYLBRRN-WSZUGLNLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(2-pyridylmethyleneamino)-N-tosylaniline 、 钴 生成 bis[2-(2-pyridylmethyleneamino)-N-tosylanilinato]cobalt(II)
  参考文献：
  名称：

  Garnovskii; Vasil'chenko; Eliseeva, Russian Journal of General Chemistry, 1999, vol. 69, # 9, p. 1473 - 1476

  摘要：

  DOI：

文献信息

• Structural characterisation of metal complexes containing 1-[(4-methylphenyl)sulfonamido]-2-[(2-pyridylmethylene) amino]benzene
  作者：Antonio Sousa、Manuel R. Bermejo、Matilde Fondo、Ana García-Deibe、Antonio Sousa-Pedrares、Oscar Piro

  DOI：10.1039/b008932j

  日期：——

  The interaction of 2-pyridinecarboxaldehyde with N-tosyl-1,2-diaminobenzene leads to the isolation of two different products, 3-[ethoxy(2-pyridyl)methyl]-1-[(4-methylphenyl)sulfonyl]-2-(2-pyridyl)-2,3-dihydro-1H-benzo[d]imidazole}, L1, and 1-[(4-methylphenyl)sulfonyl]-2-(2-pyridyl)-2,3-dihydro-1H-benzo[d]imidazole}, L2, but not to the expected Schiff base 1-[(4-methylphenyl)sulfonamido]-2-[(2-pyridylmethylene)amino]benzene, HL3. Two kinds of complexes, containing the potentially tridentate and monoanionic [L3]− as a ligand, were obtained by different routes. ML3(p-Tos)(H2O)n complexes (p-TosH =  p-toluenesulfonic acid; M = Co, Cu, Zn; n  = 1–3) have been isolated by electrolysis of a solution phase composed of L1 and p-toluenesulfonic acid, using metal plates as the anode. Metal complexes of composition ML32(H2O)n (M = Mn, Co, Cu, Zn; n  = 0–2) were obtained by template synthesis from M(acac)2, 2-pyridinecarboxaldehyde and N-tosyl-1,2-diaminobenzene. All these compounds have been characterised by elemental analyses, magnetic measurements, IR, mass spectrometry and, in the case of M = Zn, by 1H NMR spectroscopy. CuL3(p-Tos)(H2O), 1, ZnL3(p-Tos)(H2O), 2, CoL32, 3, CuL32, 4 and ZnL32·2CH3CN, 5, were also crystallographically characterised.

  L1，以及1-[(4-甲基苯基)磺酰基]-2-(2-吡啶基)-2,3-二氢-1H-苯并[d]咪唑}，L2，但不是预期的希夫碱 1-[(4-甲基苯基)磺酰氨基]-2-[(2-吡啶亚甲基)氨基]苯，HL3。通过不同的途径，得到了两种含有潜在的三叉单阴离子[L3]-作为配体的配合物。以金属板为阳极，通过电解由 L1 和对甲苯磺酸组成的溶液相，分离出了 ML3(p-Tos)(H2O)n 复合物（p-TosH = 对甲苯磺酸；M = Co、Cu、Zn；n = 1-3）。通过 M(acac)2、2-吡啶甲醛和 N-对甲苯磺酰基-1,2-二氨基苯的模板合成，获得了成分为 ML32( )n（M = Mn、Co、Cu、Zn；n = 0-2）的金属配合物。所有这些化合物都已通过元素分析、磁性测量、红外光谱、质谱以及 1H NMR 光谱（M = Zn）进行了表征。此外，还对 CuL3(p-Tos)( )、1、ZnL3(p-Tos)( )、2、CoL32、3、CuL32、4 和 ZnL32-2CH3CN 5 进行了晶体学表征。