N-Acryloyl-2,4-dimethyl-anilin | 17090-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-Acryloyl-2,4-dimethyl-anilin
• 英文别名: N-(2,4-dimethylphenyl)prop-2-enamide
• CAS: 17090-22-1
• 化学式: C₁₁H₁₃NO
• 分子量: 175.23
• InChiKey: MGZDIKRUWLTATE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 N-Acryloyl-2,4-dimethyl-anilin 在 [Au(dcpm)Cl]₂ 、 二氢吡啶 、 四甲基胍 作用下， 以 乙腈 为溶剂， 以48 %的产率得到4-chloro-N-(2,4-dimethylphenyl)butamide
  参考文献：
  名称：

  光诱导金催化的宝石二氯烷烃的发散脱氯烷基化

  摘要：

  使用烷基氯作为 C( sp 3 )-杂化亲电试剂构建 C( sp 3 )–C( sp 3 ) 键代表了有机合成中最具挑战性的问题之一，与其低还原电位和强键相关离解能。在这里，我们报告了通过激发态双核金催化对烯烃进行可控脱氯烷基化，对丰富的结构多样的宝石-二氯烷烃库进行发散式自由基转化。宝石-二氯烷烃可用于组装C( sp 3 )–C( sp 3) 作为氯烷基自由基、烷基自由基阳离子和碳链增长的卡宾当量前体键合，或烯烃的正式 [4+1] 和 [2+1] 环化。使用市售的氘标记的多氯甲烷提供了一种将 CD 2 Cl、CDCl 2、CDCl 和 CD 2部分并入有机支架的实用方法。对该机制的研究揭示了一个内球单电子转移途径，用于强 C-Cl 键的均裂裂解。

  DOI：

  10.1038/s41929-022-00881-5

文献信息

• THERMOPLASTIC RESIN COMPOSITION, OPTICAL FILM, AND PROCESS FOR PRODUCING FILM
  申请人：JSR Corporation

  公开号：EP1837374A1

  公开（公告）日：2007-09-26

  The present invention is intended to provide a thermoplastic resin composition which is inhibited from suffering phase separation and from which an optical film having excellent transparency is readily obtained, an optical film containing the composition as a main component, a retardation film which is a film obtained by stretching the optical film and exhibits positive wavelength dependence and has a small coefficient of photoelasticity and transparency, and a process for producing the retardation film. The thermoplastic resin composition contains (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a unit represented by the following formula (II): wherein at least one of R1 to R4 is a group represented by the formula (III), the remainder of R1 to R4, if any, and R5 and R6 are each a hydrogen atom, a halogen atom, a (substituted) hydrocarbon group which may have a linkage containing a hetero atom, or a polar group, R5 and R6 may be bonded to each other to form a monocyclic or polycyclic group which may have a hetero atom, or may be united to form a divalent hydrocarbon group, and Y is a divalent hydrocarbon group.

  本发明旨在提供一种热塑性树脂组合物，该组合物能抑制相分离，并能很容易地从中获得透明度极佳的光学薄膜；一种含有该组合物作为主要成分的光学薄膜；一种通过拉伸该光学薄膜而获得的延缓膜，该膜具有正波长依赖性，并具有较小的光弹性系数和透明度；以及一种生产该延缓膜的工艺。热塑性树脂组合物包含 (A) 环烯烃基聚合物和 (B) 乙烯基聚合物，其单元由下式 (II) 表示： 其中 R1 至 R4 中至少有一个是式(III)所代表的基团，R1 至 R4 的其余部分(如果有)以及 R5 和 R6 各为氢原子、卤素原子、(取代的)烃基(该烃基可能具有含杂原子的连接)或极性基团，R5 和 R6 可相互键合形成单环或多环基团，该单环或多环基团可能具有杂原子，或可结合形成二价烃基，Y 为二价烃基。
• Thermoplastic Resin Composition, Optical Film, And Process For Producing Film
  申请人：Miyaki Nobuyuki

  公开号：US20080177002A1

  公开（公告）日：2008-07-24

  The present invention is intended to provide a thermoplastic resin composition which is inhibited from suffering phase separation and from which an optical film having excellent transparency is readily obtained, an optical film containing the composition as a main component, a retardation film which is a film obtained by stretching the optical film and exhibits positive wavelength dependence and has a small coefficient of photoelasticity and transparency, and a process for producing the retardation film. The thermoplastic resin composition contains (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a unit represented by the following formula (II): wherein at least one of R 1 to R 4 is a group represented by the formula (III), the remainder of R 1 to R 4 if any, and R 5 and R 6 are each a hydrogen atom, a halogen atom, a substituted) hydrocarbon group which may have a linkage containing a hetero atom, or a polar group, R 5 and R 6 may be bonded to each other to form a monocyclic or polycyclic group which may have a hetero atom, or may be united to form a divalent hydrocarbon group and Y is a divalent hydrocarbon group.