[Ag(1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane)]CF3SO3 | 517863-44-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: [Ag(1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane)]CF3SO3
• CAS: 517863-44-4
• 化学式: CF₃O₃S*C₁₈H₁₈AgN₄O₂
• 分子量: 579.305
• InChiKey: YGLQQJPVGGLREU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  silver trifluoromethanesulfonate 、 1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane 以 乙醇 、 乙腈 为溶剂， 以72%的产率得到[Ag(1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane)]CF3SO3
  参考文献：
  名称：

  Low-dimensional framework constructed by silver(I) trifluoromethylsulfonate with 1,5-bis(benzimidazol-2-yl)-3-oxapentane or 1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane

  摘要：

  The ligands 1,6-bis(benzimidazol-2-yl)-2,5-dioxahexane (DEBIm) and 1,5-bis(benzimidazol-2-yl)-3-oxapentane (DEBIm) reacted with silver(l) trifluoromethylsulfonate producing [Ag(OEBIm)](CF3SO3) (1) and [Ag(DEBIm)](CF3SO3) (2), respectively. The cation [Ag(L)](+) (L = OEBIm or DEBIm) in both complexes is bent in semi-enclosed form due to the presence of oxygen in the ligands which forms either coordination bond or weak non-bonding interaction with the Ag(I) ion. Crystallographic analyses showed that [Ag(DEBIm)](+) (in 1) and [Ag(OEBIm)](+) (in 2) are assembled differently by the anion CF3SO3- via hydrogen bond N(C)-H... O to give 1-D chain and via N-H... O and C-H... F to give 2-D network, respectively. The complexes were also identified by IR and H-1 NMR spectroscopy. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01153-2