Phenylimino-phenylaethylketen | 14303-52-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenylimino-phenylaethylketen
• CAS: 14303-52-7
• 化学式: C₁₆H₁₅N
• 分子量: 221.302
• InChiKey: LSFSGOKMJYVSKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Phenylimino-phenylaethylketen 在 盐酸 作用下， 生成 2-ethyl-2-phenyl-N-phenylacetamide
  参考文献：
  名称：

  Phosphoramidate Anions. The Preparation of Carbodiimides, Ketenimines, Isocyanates, and Isothiocyanates¹

  摘要：

  DOI：

  10.1021/jo01033a002
• 作为产物：
  描述：

  2-苯基-1-丁烯-1-酮 、 N-苯基-氨基磷酸二乙酯 生成 Phenylimino-phenylaethylketen
  参考文献：
  名称：

  Phosphoramidate Anions. The Preparation of Carbodiimides, Ketenimines, Isocyanates, and Isothiocyanates¹

  摘要：

  DOI：

  10.1021/jo01033a002

文献信息

• Synthesis, electrochemistry and reactivity of formato– and acetato–niobocene complexes
  作者：Antonio Antiñolo、Mariano Fajardo、Santiago García-Yuste、Isabel Del Hierro、Antonio Otero、Soumia Elkrami、Youssef Mourad、Yves Mugnier

  DOI：10.1039/dt9950003409

  日期：——

  The complex [Nb(eta(5)-C(5)H(4)SiMe(3))(2)H-3] 1 reacted with CO2 to give the formato complex [Nb(eta(5)-C(5)H(4)SiMe(3))(2)OC(O)H-O,O'}] 2, which can alternatively be prepared from a two-electron reduction of [Nb(eta(5)-C(5)M(4)SiMe(3))(2)Cl-2] 3 in the presence of formic acid. the reaction of 2 with different pi-acids or heterocumulene molecules resulted in opening of the bidentate formate ligand giving rise to the monodentate formato-containing complexes [Nb(eta 5-C(5)H(4)SiMe(3))(2)OC(O)H-O}L], L = CS2 4, CO 5 or 2,6-Me(2)C(6)H(3)NC 6. On the other hand; [Nb(eta(5)-C(5)H(4)SiMe(3))(2)OC(O)Me-O,O'}] 8 was prepared from either the reaction of [Nb(eta(5)-C(5)H(4)SiMe(3))(2)Cl] 7 with 1 equivalent of TI(O(2)CMe) or from a two-electron reduction of 3 in the presence of acetic acid. The complex [Nb(eta(5)-C(5)H(4)SiMe(3))(2)(MeCOCHCOMe-O,O')] 9 can also be isolated from the reaction of 7 with 1 equivalent of Tl(acac) (acac = acetylacetonate). Complex 8 reacted with oxygen to give [Nb(eta(5)-C(5)H(4)SiMe(3))(2)OOC(O)Me-O}] 10, and with pi-acids or heterocumulenes to give products with a monodentate OC(O)Me ligand, namely [Nb(eta(5)-C(5)H(4)SiMe(3))(2)OC(O)Me-O}L], L = CS2 11, SCNPh 12, PhNCCPhEt 13, MeO(2)CC=CCO(2)Me 14, Bu(t)NC 15 or CO 16. The structures of all complexes have been established by spectroscopic methods.
• MINAMI T.; TAKIMOTO F.; AGAWA T., BULL. CHEM. SOC. JAP. <BCSJ-A8>, 1975, 48, NO 11, 3259-3261
  作者：MINAMI T.、 TAKIMOTO F.、 AGAWA T.

  DOI：——

  日期：——