| 592531-72-1

• 分子结构分类: 有机化合物
• CAS: 592531-72-1
• 化学式: C₃₂H₂₈N₈O₈S₂Zn₂
• 分子量: 847.535
• InChiKey: KMIDTMHMOCPAFZ-VLRNVLOZSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-[2'-hydroxysalicylidene-5'-(2''-thiazolylazo)]phenol 、 zinc(II) chloride 在 NH₃ 作用下， 以 乙醇 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Studies on Some Binuclear Metal Complexes with Tetradentate Ligand Derived from 5‐(2′‐Thiazolylazo)salicylaldehyde and 2‐Aminophenol

  摘要：

  The Schiff base ligand 2-[2'-hydroxysalicylidene-5'-(2"-thiazolylazo)]phenol was prepared and characterized. The ligand yields binuclear complexes of the type [ML(H2O)(2)](2) [H2L=2-[2'-hydroxysalicylidene-5'- (2"-thiazolyl azo] phenol, M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)] have been synthesized and characterized by elemental analyses, magnetic susceptibility, molar conductance, IR, electronic spectra and thermal analysis (TGA). The ESR spectra of the Cu(II) complex were studied resulting in g(parallel to) > g(perpendicular to) > 2.0023. The N2O2 environment of the metal ion is realized in the complexes by involvement of the -N=N- group in coordination. The magnetic moments and electronic spectra indicate octahedral geometry for the Mn(II), Co(II), Ni(II) and Zn(II) complexes and distorted octahedral geometry for the Cu(II) complex.

  DOI：

  10.1081/sim-120019996