adipic acid bis-(2-methoxy-phenyl ester) | 111797-20-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: adipic acid bis-(2-methoxy-phenyl ester)
• 英文别名: Adipinsaeure-bis-(2-methoxy-phenylester)；Bis(2-methoxyphenyl) hexanedioate
• CAS: 111797-20-7
• 化学式: C₂₀H₂₂O₆
• 分子量: 358.391
• InChiKey: VFOCYWCDPBKUPN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  己二酸 、 木榴油 在 三氯氧磷 作用下， 生成 adipic acid bis-(2-methoxy-phenyl ester)
  参考文献：
  名称：

  Selisko, 1957, vol. 2, p. 362

  摘要：

  DOI：

文献信息

• AROMATIC POLYCARBONATE RESIN COMPOSITION
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2921516A1

  公开（公告）日：2015-09-23

  The present invention provides an aromatic polycarbonate resin composition having a high molecular weight and less amount of a heterologous structure, retaining good qualities, and excellent in thermal stability, and an improved preparation process thereof.

  本发明提供了一种芳香族聚碳酸酯树脂组合物，其分子量高，异源结构含量少，质量好，热稳定性优异，并改进了其制备工艺。
• PRODUCTION METHOD FOR AROMATIC POLYCARBONATE RESIN HAVING INCREASED MOLECULAR WEIGHT
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2921515A1

  公开（公告）日：2015-09-23

  The invention provides a process for producing a highly polymerized aromatic polycarbonate resin including a molecular weight-increasing step of reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound represented by Formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin. In the formula, Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, a cycloalkyl group, an aryl group or an alkoxy group, or Ra and Rb may be bonded to each other to form a ring; R1 to R4 each independently represent a hydrogen atom, a halogen atom or an alkyl group; and n represents an integer of 0 to 30.

  本发明提供了一种生产高度聚合的芳香族聚碳酸酯树脂的工艺，包括一个增加分子量的步骤，即在酯交换催化剂存在下，芳香族聚碳酸酯预聚物与由式（g2）表示的脂肪族二元醇化合物反应，得到高度聚合的芳香族聚碳酸酯树脂。式中，Ra 和 Rb 各自独立地代表氢原子、卤素原子、直链或支链烷基、环烷基、芳基或烷氧基，或 Ra 和 Rb 可相互键合形成环；R1 至 R4 各自独立地代表氢原子、卤素原子或烷基；n 代表 0 至 30 的整数。
• High-fluidity polycarbonate copolymer, process for production highly polymerized aromatic polycarbonate resin and aromatic polycarbonate compound
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US10053537B2

  公开（公告）日：2018-08-21

  Copolymer having high fluidity and high molecular weight which is formed of a structural unit derived from an aliphatic diol compound and a structural unit derived from an aromatic dihydroxy compound. A polycarbonate resin composition is also provided comprising a highly polymerized aromatic polycarbonate resin as a main component and also comprising cyclic carbonate present in an amount of not more than 3000 ppm, wherein the highly polymerized aromatic polycarbonate resin is produced by a process which comprises a highly-polymerizing process wherein an aromatic polycarbonate is reacted with an aliphatic diol compound in the presence of a transesterification catalyst to increase the molecular weight.

  具有高流动性和高分子量的共聚物，该共聚物由源自脂肪族二元醇化合物的结构单元和源自芳香族二羟基化合物的结构单元组成。本发明还提供了一种聚碳酸酯树脂组合物，其主要成分为高度聚合的芳香族聚碳酸酯树脂，还包括含量不超过 3000 ppm 的环碳酸盐，其中高度聚合的芳香族聚碳酸酯树脂是通过高度聚合工艺生产的，该工艺包括芳香族聚碳酸酯与脂肪族二元醇化合物在酯交换催化剂存在下发生反应以增加分子量的过程。
• PROCESS FOR THE PRODUCTION OF POLYCARBONATE
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1363962A2

  公开（公告）日：2003-11-26
• PROCESS FOR PRODUCTION OF HIGHLY POLYMERIZED AROMATIC POLYCARBONATE RESIN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2502949B1

  公开（公告）日：2019-07-24