zinc phenylphosphonate monohydrate | 122780-95-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: zinc phenylphosphonate monohydrate
• 英文别名: zinc phenylphosphate monohydrate；zinc;dioxido-oxo-phenyl-λ5-phosphane;hydrate
• CAS: 122780-95-4；45986-33-2
• 化学式: C₆H₅O₃P*H₂O*Zn
• 分子量: 239.483
• InChiKey: QCCZHLZTSRCUMX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  64.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  zinc phenylphosphonate monohydrate 以 neat (no solvent) 为溶剂， 生成 zinc phenylphosphonate
  参考文献：
  名称：

  Frink, Karen J.; Wang, Ren-Chain; Colón, Jorge L., Inorganic Chemistry, 1991, vol. 30, # 7, p. 1438 - 1441

  摘要：

  DOI：
• 作为产物：
  描述：

  zinc phenylphosphonate 在 H₂O 作用下， 以 neat (no solvent) 为溶剂， 生成 zinc phenylphosphonate monohydrate
  参考文献：
  名称：

  Frink, Karen J.; Wang, Ren-Chain; Colón, Jorge L., Inorganic Chemistry, 1991, vol. 30, # 7, p. 1438 - 1441

  摘要：

  DOI：

文献信息

• Thermal Behavior of Zinc Phenylphosphonate and Structure Determination ofγ-Zn2P2O7from X-Ray Powder Diffraction Data
  作者：T. Bataille、P. Bénard-Rocherullé、D. Louër

  DOI：10.1006/jssc.1998.7854

  日期：1998.10

  The thermal behavior of zinc phenylphosphonate has been studied by temperature-dependent X-ray powder diffraction and thermo-gravimetry in the temperature range 19–600°C. The different phases occurring during the decomposition have been identified, i.e., the anhydrous phase and the three successive polymorphic varieties of Zn2P2O7. The first one is amorphous,δ-Zn2P2O7is poorly crystalline, andγ-Zn2P2O7is

  通过在19–600°C的温度范围内通过温度依赖性X射线粉末衍射和热重分析法研究了苯基膦酸锌的热行为。已经确定了在分解过程中发生的不同相，即无水相和Zn 2 P 2 O 7的三个连续的多态变体。第一个是非晶态的，δ- Zn 2 P 2 O 7的结晶性较差，而γ- Zn 2 P 2 O 7的则是亚稳相。最后一个在较高温度下转变为β变体。γ的晶体结构-Zn 2 P 2 O 7从头开始是用常规单色X射线收集的粉末衍射数据解决的。对称性是正交的，单元尺寸为a = 4.9504（5）Å，b = 13.335（2）Å，c = 16.482（3）Å，空间群Pbcm，Z = 8。该结构由沿着[001]延伸的ZnO 5三角双锥体的无限波纹链组成。这些链通过另外两个方向的P 2 O 7基团连接在一起。P 2 O 4− 7与α和β相相反，阴离子显示出低角度和黯淡的构象。
• An organometallic sol–gel route to layered zinc phenylphosphonate and encapsulation studies with η6-(C6H6)Cr(CO)3
  作者：Robert W Deemie、Muralidhar Rao、D.Andrew Knight

  DOI：10.1016/s0022-328x(99)00209-0

  日期：1999.8

  white gel. The gel was dried in air at room temperature for 8 h to give the layered compound [ZnC6H5PO3]·H2O (1). This process represents a convenient non-aqueous organometallic sol–gel route to a layered metal phosphonate material. Zinc phenylphosphonate synthesized using the sol–gel method is identical to that prepared using the conventional aqueous precipitation technique as determined by IR spectroscopy

  苯膦酸与二乙基锌在甲苯/ THF中反应，得到白色凝胶。将该凝胶在室温下在空气中干燥8小时，得到层状化合物[ZnC 6 H 5 PO 3 ]·H 2 O（1）。此过程代表了一种方便的非水有机金属溶胶-凝胶路线，可用于形成层状金属膦酸酯材料。溶胶-凝胶法合成的苯基膦酸锌与通过红外光谱，热重分析和粉末X射线衍射法测定的使用常规水相沉淀技术制备的磷酸锌相同。η 6 - （C 6 H ^ 6）的Cr（CO）3 在缩合反应期间可以将其结合到凝胶中。
• Tailoring the photoluminescence properties of transition metal phosphonates
  作者：Richard Singleton、James Bye、James Dyson、Gary Baker、Robert M. Ranson、Gary B. Hix

  DOI：10.1039/c000531b

  日期：——

  A series of phenylphosphonates, Zn1−xMnx(O3PC6H5)·H2O, where x = 0, 0.005, 0.25, 0.5, 0.75 and 1.0, has been prepared and their photoluminescence responses studied. The presence of Mn in the sample results in a red emission, whilst when x = 0 the emission is green. Levels of Mn <1 mol% result in an orange emission. Ag6(m-O3PC6H4CO2)2 has been prepared by hydrothermal reaction of Ag(NO3) and m-phosphonobenzoic acid. The material has a 1D channel structure in which the channels are lined with the phenyl groups. Ag6(m-O3PC6H4CO2)2 shows a green luminescence response to laser excitation, whilst the related Zn material, Zn3(m-O3PC6H4CO2)2, shows an unusual yellow emission.

  制备了一系列苯基膦酸酯 Zn1−xMnx(O3PC6H5)·H2O，其中 x = 0、0.005、0.25、0.5、0.75 和 1.0，并研究了它们的光致发光响应。样品中 Mn 的存在导致红色发射，而当 x = 0 时，发射呈绿色。 Mn 含量<1 mol% 会导致橙色发射。 Ag6(m-O3PC6H4CO2)2 通过 Ag(NO3) 和间膦酰基苯甲酸的水热反应制备。该材料具有一维通道结构，其中通道排列有苯基。 Ag6(m-O3PC6H4CO2)2 对激光激发显示出绿色发光响应，而相关的 Zn 材料 Zn3(m-O3PC6H4CO2)2 显示出不寻常的黄色发射。
• Divalent metal phenylphosphonates and phenylarsonates
  作者：Desmond Cunningham、Patrick J.D. Hennelly、Tony Deeney

  DOI：10.1016/s0020-1693(00)95524-5

  日期：1979.1
• Selected-Control Synthesis of Metal Phosphonate Nanoparticles and Nanorods
  作者：Shu-Yan Song、Jian-Fang Ma、Jin Yang、Min-Hua Cao、Ke-Chun Li

  DOI：10.1021/ic048436t

  日期：2005.4.1

  By surfactant-assisted methods, nanoscale Co(O3PC6H5)center dot H2O species of different morphologies, namely, nanoparticles and nanorods, have been successfully synthesized and characterized. Upon removal of the organic part of the compound, peculiar Co2P2O7 porous nanorods formed.