(Z)-1-(chlorodi-p-tolylstannyl)-3-phenyl-1-buten-3-ol | 670250-94-9

• 英文名称: (Z)-1-(chlorodi-p-tolylstannyl)-3-phenyl-1-buten-3-ol
• CAS: 670250-94-9
• 化学式: C₂₄H₂₅ClOSn
• 分子量: 483.625
• InChiKey: OFKSLRXKNHTSTA-USOZLSCGSA-M

物化性质

• 熔点：
  133.6-134.8 °C(Solv: cyclohexane (110-82-7))
• 沸点：
  538.3±60.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-苯基-3-丁炔-2-醇 以 四氯化碳 、 乙醚 为溶剂， 生成 (Z)-1-(chlorodi-p-tolylstannyl)-3-phenyl-1-buten-3-ol
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of (Z)-1-(triarylstannyl)-3-phenyl-1-buten-3-ols and their arylhalostannyl derivatives

  摘要：

  (Z)-1-(tri-o-tolylstannyl)-3-phenyl-1-buten-3-ol (1) and (Z)-1-(tri-p-tolylstannyl)-3-phenyl-1-buten-3-ol (2) were synthesized by the additive reaction of 3-phenyl-1-butyn-3-ol with tri-o-tolyltin and tri-p-tolyltin hydrides. One of the aryl groups in compounds I and 2 was substituted by Cl, Br, I to yield derivatives of the type PhC(CH3)(OH)CH=CHSn(aryl)(2)X [aryl=o-tolyl, X=Cl (3); aryl=p-tolyl, X=Cl (4); aryl=o-tolyl, X=Br (5); aryl=p-tolyl, X=Br (6); aryl=o-tolyl, X=I (7); aryl=p-tolyl, X=I (8)]. Compounds 1-8 were characterized by elemental analysis; H-1 NMR and FT-IR spectroscopy. The crystal structures of 1, 2 and 5 have been determined by single crystal X-ray diffraction analysis. The Sn atom in 1 and 2 exhibits tetrahedral geometry distorted towards trigonal bipyramidal due to a weak intramolecular interaction between Sn and the hydroxyl 0 atoms [2.879(5) and 2.859(4) Angstrom], while the Sn atom in 5 adopts a trigonal bipyramidal geometry with a significant Sn(1) <-- O interaction [2.483(4) Angstrom]. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.09.012