2-diphenylphosphanyl-6-trimethylsilylbenzenethiolate;nickel(2+) | 220171-81-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-diphenylphosphanyl-6-trimethylsilylbenzenethiolate;nickel(2+)
• CAS: 220171-81-3
• 化学式: C₄₂H₄₄NiP₂S₂Si₂
• 分子量: 789.752
• InChiKey: ZKLRIPDFKOFPJW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.79
• 重原子数：
  49.0
• 可旋转键数：
  6.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  镍 、 苯硫醇,2-(二苯基膦基)-6-(三甲基甲硅烷基)- 以 乙腈 为溶剂， 以86%的产率得到2-diphenylphosphanyl-6-trimethylsilylbenzenethiolate;nickel(2+)
  参考文献：
  名称：

  Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands. Crystal and molecular structures of [Co{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }3], [Ni{ {2- (Ph2P)-6- (Me3Si)C6H3S)} }2] and [Co{ {2- (Ph2PO)-6- (Me3Si)C6H3S} }2]

  摘要：

  The electrochemical oxidation of anodic metal (cobalt or nickel) in an acetonitrile solution of phosphinothiol ligands. 2-(Ph2P)C6H4SH, 2-(Ph2P)-6-(SiMe3)C6H3SH, 2-(Ph2PO)-6- (SiMe3)C6H3SH, affords [Co{2-(Ph2P)C6H4S)}(3)] 1, [Ni{2-(Ph2P)C6H4S}(2)] 2, [Co{2-(Ph2P)-6-(SiMe3)C6H3S}(3)] 3, [Ni{2-(Ph2P)-6-(SiMe3) C6H3S}(2)] 4, [Co{2-(Ph2PO)-6-(SiMe3)C6H3S}(2)] 5, [Co{2-(Ph2PO)-6- (SiMe3)C6H3S}(3)] 6 and [Ni{2-(Ph2PO)-6-(SiMe3)C6H3S}(2)] 7. All compounds have been characterised by microanalysis, TR. UV-visible. FAB and NMR spectroscopic studies and compounds 3, 4 and 5 by single-crystal X-ray diffraction. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00252-6