methylsparteinium hydroxide | 154726-68-8

• 分子结构分类: 有机化合物 - 生物碱及其衍生物 - 羽扇豆生物碱
• 英文名称: methylsparteinium hydroxide
• 英文别名: (1S,2R,9S,10S)-7-methyl-15-aza-7-azoniatetracyclo[7.7.1.02,7.010,15]heptadecane;hydroxide
• CAS: 154726-68-8
• 化学式: C₁₆H₂₉N₂*HO
• 分子量: 266.427
• InChiKey: QTMREHILWWWWMN-STJZPPTESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  4.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  sparteine sulphate pentahydrate 、 碘甲烷 在 sodium chloride 作用下， 以 sodium hydroxide 、 丙酮 为溶剂， 生成 methylsparteinium hydroxide
  参考文献：
  名称：

  US2001/34467

  摘要：

  公开号：

文献信息

• CFI-type zeolite, its preparation, catalyst containing it, use thereof for conversion of organic compounds
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1136121A2

  公开（公告）日：2001-09-26

  A CFI-type zeolite where the atomic ratio of silicon to a heteroatom is 45 or less and the long axes of the crystals are 0.7 µm or less is useful as a catalyst for conversion reactions of aromatic compounds because the zeolite has a number of active sites and small crystals.

  硅与杂原子的原子比为 45 或以下、晶体长轴为 0.7 微米或以下的 CFI 型沸石可用作芳香族化合物转化反应的催化剂，因为这种沸石具有许多活性位点和小晶体。
• USE OF ZEOLITE ITQ-21 IN THE CATALYTIC CRACKING OF ORGANIC COMPOUNDS
  申请人：CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS

  公开号：EP1445297A1

  公开（公告）日：2004-08-11

  The present invention relates to the use of zeolite ITQ-21 in a process of catalytic cracking of organic compounds. In said cracking process the zeolite ITQ-21 can be present in the catalyst as the sole zeolite component of same of combined with at least one second zeolite component. Moreover, said zeolite ITQ-21 can be present in the catalyst as unmodified zeolite ITQ-21 or as ITQ-21 modified zeolite. The preferred combinations, wherein the zeolite forms part of the cracking catalyst, are those wherein it is combined with at least one second zeolite component. The preferred modifications comprise, for example, a modification by means of post-synthesis treatment with phosphorous or a modification involving the introduction of acid centres. The catalytic procxess is preferably an FCC or DPC type hydrocarbon cracking process

  本发明涉及沸石 ITQ-21 在有机化合物催化裂解工艺中的应用。在所述裂解工艺中，沸石 ITQ-21 可以作为催化剂中唯一的沸石组分，也可以与至少一种第二沸石组分结合使用。此外，所述沸石 ITQ-21 可以作为未改性沸石 ITQ-21 或 ITQ-21 改性沸石存在于催化剂中。沸石构成裂解催化剂一部分的优选组合是它与至少一种第二沸石组分相结合的组合。优选的改性包括，例如，通过合成后磷处理或引入酸中心的改性。催化过程最好是 FCC 或 DPC 类型的碳氢化合物裂解过程
• CFI-type zeolite, process for preparation of the same, catalyst prepared from the same, and process for conversion of organic compounds
  申请人：——

  公开号：US20010034467A1

  公开（公告）日：2001-10-25

  A CFI-type zeolite where the atomic ratio of silicon to the heteroatom is 45 or less and the long axes of the crystals are 0.7 &mgr;m or less is useful as a catalyst for conversion reaction of aromatic compounds because the zeolite has a number of active sites and small crystals.

  硅与杂原子的原子比为 45 或以下、晶体长轴为 0.7 或以下的 CFI 型沸石可用作芳香族化合物转化反应的催化剂，因为这种沸石具有许多活性位点和较小的晶体。
• Process for conversion of organic compounds
  申请人：Toray Industries, Inc.

  公开号：US20040038804A1

  公开（公告）日：2004-02-26

  A process for conversion of organic compounds including contacting a catalyst formed from a CFI-type zeolite including an atomic ratio of silicon to a heteroatom of 45 or less, and long axes of crystals of 0.7 &mgr;m or less with the organic compounds.

  一种有机化合物的转化工艺，包括将由 CFI 型沸石（硅与杂原子的原子比为 45 或以下，晶体长轴为 0.7 或以下）形成的催化剂与有机化合物接触。
• Use of zeolite ITQ-21 in the catalytic cracking of organic compounds
  申请人：——

  公开号：US20040256291A1

  公开（公告）日：2004-12-23

  The present invention relates to the use of zeolite ITQ-21 in a process of catalytic cracking of organic compounds. In said cracking process the zeolite ITQ-21 can be present in the catalyst as the sole zeolite component of same of combined with at least one second zeolite component. Moreover, said zeolite ITQ-21 can be present in the catalyst as unmodified zeolite ITQ-21 or as ITQ-21 modified zeolite. The preferred combinations, wherein the zeolite forms part of the cracking catalyst, are those wherein it is combined with at least one second zeolite component. The preferred modifications comprise, for example, a modification by means of post-synthesis treatment with phosphorous or a modification involving the introduction of acid centres. The catalytic procxess is preferably an FCC or DPC type hydrocarbon cracking process.

  本发明涉及沸石 ITQ-21 在有机化合物催化裂解工艺中的应用。在所述裂解工艺中，沸石 ITQ-21 可以作为催化剂中唯一的沸石组分，也可以与至少一种第二沸石组分结合使用。此外，所述沸石 ITQ-21 可以作为未改性沸石 ITQ-21 或 ITQ-21 改性沸石存在于催化剂中。沸石构成裂解催化剂一部分的优选组合是它与至少一种第二沸石组分相结合的组合。优选的改性包括，例如，通过合成后磷处理或引入酸中心的改性。催化过程最好是 FCC 或 DPC 类型的碳氢化合物裂解过程。