[Ir(2-phenylthiazole(-H)-N,C2)2(acetylacetonate)] | 866035-90-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ir(2-phenylthiazole(-H)-N,C2)2(acetylacetonate)]
• CAS: 866035-90-7
• 化学式: C₂₃H₁₉IrN₂O₂S₂
• 分子量: 611.768
• InChiKey: WNICBPIZLPRWCA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ir(ptz)₂Cl]₂ 、 乙酰丙酮 以 further solvent(s) 为溶剂， 以19%的产率得到[Ir(2-phenylthiazole(-H)-N,C2)2(acetylacetonate)]
  参考文献：
  名称：

  Color tunable phosphorescent iridium complexes with substituted 2-phenylthiazoles as the cyclometalated ligands

  摘要：

  Several new iridium complexes with substituted 2-phenylthiazoles as the cyclometalated ligands have been synthesized and characterized to try to investigate the effect of the size of the pi system and substituent groups on physical properties. The complexes have the general structure of (C(Lambda)N)(2)Ir(acac), where the C(Lambda)N are 2-phenylthiazole (ptz), 2-(4-methylphenyl)thiazole (mptz), 2-(4-ethylphenyl)thiazole (eptz). The absorption, emission, cyclic voltammetry and thermostability of the complexes were systematically investigated. The experimental results revealed that the maximum emission wavelength in CH(2)Cl(2) at room temperature are in the range 542-547 nm, which is blue shift than that of the known iridium(III) bis(2-phenylbenzothiazolato-N,C(2')) acetyl acetonate (bt)(2)Ir(acac) due to decreasing the size of the pi system in the benzothiazole portion of 2- phenylbenzothiazole ligand. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.04.047