Rh(phthalocyanine)I | 42494-77-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: Rh(phthalocyanine)I
• CAS: 42494-77-9
• 化学式: C₃₂H₁₆N₈*I*Rh
• 分子量: 742.343
• InChiKey: BOBIBICICIEPPV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  42.0
• 可旋转键数：
  0.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105.54
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  Rh(phthalocyanine)I 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  The Charge transfer and ligand centered excited state photochemistries of the first and second row d6-transition metal phthalocyanines

  摘要：

  DOI：

  10.1016/s0020-1693(00)90263-9
• 作为产物：
  描述：

  碘化钕(III)水合物 、 2-氰基苯甲酰胺 生成 Rh(phthalocyanine)I
  参考文献：
  名称：

  Dynamics of the triplet state of phthalocyanine complexes of the platinum metals in zero field

  摘要：

  The luminescence properties of phthalocyanine complexes of platinum metals with d6 and d8 electron configurations were investigated in dilute solutions between room temperature and 1.6°K. For the first time it was possible to study the magnetic sublevels of the triplet state of aromatic molecules in zero field through optical detection methods alone. It was found that the lowest triplet state of these molecules has three zero field components of unequal splitting which depends on the central metal ion and which ranges from approximately 0.1–-10 cm−-1. Intersystem crossing populates solely the highest triplet component which does not radiate to the ground state, but which, in turn, populates the lower lying triplet components. The spin-lattice relaxation rates of these processes could be estimated to be of the order of 105 sec−1 at liquid helium temperature, and the triplet to ground state (S0← T1) decay rates were obtained. A noticeable solvent dependence of the radiationless rates was observed. The effect of spin-orbit coupling and radiationless energy transfer as a function of the metal ion in the phthalocyanine complexes is discussed. Surprisingly, Pd and Rh phthalocyanine were found to fluoresce as well as phosphoresce from essentially ligand-centered,excited states, an unusual occurrence in open d shell transition metal complexes.

  DOI：

  10.1063/1.1679197

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B2, 2.5.2.2, page 234 - 235
  作者：

  DOI：——

  日期：——