申请人:Dow Global Technologies LLC
公开号:EP3578574A1
公开(公告)日:2019-12-11
The present invention relates to a method comprising the steps of: a) contacting an acrylate monomer, a carboxylic acid monomer, and a chain transfer agent under free radical polymerization conditions to form a solution of a polymer having an Mn in the range of from 5,000 to 50,000 Daltons; b) contacting the solution with a base and an ethylenically unsaturated glycidyl functionalized monomer to form a solution of an ethylenically unsaturated acrylate polymer; c) contacting the solution of the ethylenically unsaturated functionalized acrylate polymer with water to form an aqueous dispersion of ethylenically unsaturated functionalized acrylate polymers; and d) removing the organic solvent. The method of the present invention provides a composition suitable for use as a UV curable coating that achieves an excellent balance of hardness, flexibility, and warmth with less reliance on costly MFAs.
本发明涉及一种方法,包括以下步骤a) 在自由基聚合条件下,将丙烯酸酯单体、羧酸单体和链转移剂接触,形成 Mn 在 5,000 至 50,000 道尔顿范围内的聚合物溶液; b) 将溶液与碱和乙烯基不饱和缩水甘油官能化单体接触,形成乙烯基不饱和丙烯酸酯聚合物溶液;c) 将乙烯基不饱和官能化丙烯酸酯聚合物溶液与水接触,形成乙烯基不饱和官能化丙烯酸酯聚合物的水分散液;以及 d) 去除有机溶剂。本发明的方法提供了一种适合用作紫外线固化涂料的组合物,该组合物在硬度、柔韧性和保暖性方面达到了极佳的平衡,同时减少了对昂贵的 MFA 的依赖。