[N-methyl-3,5-bis(diphenylphosphinothioyl)pyridinium-C(4),S,S']iodopalladium(II) iodide | 1021497-59-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [N-methyl-3,5-bis(diphenylphosphinothioyl)pyridinium-C(4),S,S']iodopalladium(II) iodide
• CAS: 1021497-59-5
• 化学式: C₃₀H₂₅INP₂PdS₂*I
• 分子量: 885.844
• InChiKey: JYMWSWQEAHCOPL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [N-methyl-3,5-bis(diphenylphosphinothioyl)pyridinium-C(4),S,S']iodopalladium(II) iodide 、 乙腈 以 not given 为溶剂， 生成 [N-methyl-3,5-bis(diphenylphosphinothioyl)pyridinium-C(4),S,S']iodopalladium(II) hexafluorophosphate bis(acetonitrile) adduct
  参考文献：
  名称：

  Synthesis, structure, and quaternization and complexation reactions of κ3SCS pincer palladium complexes having 3,5-pyridinediyl unit

  摘要：

  The cyclopalladation of 3,5-bis(diphenylphosphinothioyl) pyridine afforded new kappa S-3,C,S-pincer palladium complexes with a sigma-bond between Pd and 4C of the centered 3,5-pyridinediyl unit. By utilizing the quaternization and complexation ability of the pyridine imine nitrogen (N-py) atom, various new pincer-type complexes, including hetero-binuclear complexes, have been synthesized. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.033
• 作为产物：
  描述：

  3,5-bis(diphenylphosphinothioyl)pyridine 在 NaCH₃COO 、 AgBF₄ 作用下， 以 四氢呋喃 为溶剂， 生成 [N-methyl-3,5-bis(diphenylphosphinothioyl)pyridinium-C(4),S,S']iodopalladium(II) iodide
  参考文献：
  名称：

  Synthesis, structure, and quaternization and complexation reactions of κ3SCS pincer palladium complexes having 3,5-pyridinediyl unit

  摘要：

  The cyclopalladation of 3,5-bis(diphenylphosphinothioyl) pyridine afforded new kappa S-3,C,S-pincer palladium complexes with a sigma-bond between Pd and 4C of the centered 3,5-pyridinediyl unit. By utilizing the quaternization and complexation ability of the pyridine imine nitrogen (N-py) atom, various new pincer-type complexes, including hetero-binuclear complexes, have been synthesized. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.033