| 1242436-11-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• CAS: 1242436-11-8
• 化学式: C₄₂H₂₂F₁₂O₂
• 分子量: 786.616
• InChiKey: VIYAVYCSGOLMJS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Cruciform-Silica Hybrid Materials

  摘要：

  AbstractSilica scaffolding: By employing functionalized mesoporous SBA‐15 silica, novel fluorescent cruciform‐silica hybrid materials are generated which preserve the desirable solution properties of cruciforms in the solid state for potential use in sensory schemes.magnified imagePreserving the solution properties of functional fluorophores upon incorporation into solid state sensory schemes remains a significant challenge. To address this concern, a silica scaffold was employed to support functional fluorophores in the solid state. Herein, we report an effort to support 1,4‐distyryl‐2,5‐bisarylethynylbenzene cruciforms (XFs) using functionalized mesoporous silica particles. By employing surface‐functionalized mesoporous SBA‐15 silica, novel fluorescent cruciform‐silica hybrid materials are generated which retain the desirable solution properties of cruciforms in the solid state. Organic surface functionalities, such as acidic, basic, and hydrophobic groups employed on the silica scaffold, modulate the observed emissions of the resulting solid state materials. The potential of these XF‐silica hybrid materials to display sensory responses to representative vapor‐phase analytes is demonstrated.

  DOI：

  10.1002/asia.200800316