2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(phenylethynyl)-29H,31H-phthalocyaninatocobalt(II) | 825635-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: 2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(phenylethynyl)-29H,31H-phthalocyaninatocobalt(II)
• 英文别名: cobalt(2+);6,7,15,16,24,25-hexakis(hexylsulfanyl)-33,34-bis(2-phenylethynyl)-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31(36),32,34-nonadecaene
• CAS: 825635-22-1
• 化学式: C₈₄H₉₆CoN₈S₆
• 分子量: 1469.13
• InChiKey: XSPVYAXSIHIDEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-dicyano-4,5-bis(hexylthio)benzene 、 cobalt(II) chloride 、 4,5-di(phenylethynyl)phthalonitrile 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 戊醇 为溶剂， 以8%的产率得到2,3,9,10,16,17-hexakis(hexylthio)-23,24-bis(phenylethynyl)-29H,31H-phthalocyaninatocobalt(II)
  参考文献：
  名称：

  Unsymmetrical phthalocyanines with alkynyl substituents

  摘要：

  The synthesis of unsymmetrically substituted metallophthalocyanines (M = Zn, Ni, Co) bearing two phenylethyl moieties and six alkythio substituents was achieved by co-cyclotetramerization of two different phthalonitrile derivatives, namely 4,5-di(hexyl-thio)phthalonitrile and 4,5-di(phenylethynyl)phthalonitrile in the presence of zinc, cobalt or nickel salts. In contrast to the totally alkyne substituted phthalocyanines, these partially alkyne-containing derivatives are more soluble and their Q band absorptions are red-shifted when compared with all alkylthio phthalocyanines. Electrochemical properties of the phthalocyanines were studied by cyclic voltammetry. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.09.021