sodium N-(P,P-diphenylphosphinoyl)-P,P-diphenylphosphinimidate | 135823-11-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: sodium N-(P,P-diphenylphosphinoyl)-P,P-diphenylphosphinimidate
• 英文别名: sodium tetraphenylimidodiphosphinate；NaTPIP；Na(tetraphenylimidodiphosphinate)；Na((OPPh2)2N)；sodium;diphenylphosphorylimino-oxido-diphenyl-λ5-phosphane
• CAS: 135823-11-9
• 化学式: C₂₄H₂₀NO₂P₂*Na
• 分子量: 439.366
• InChiKey: VOEMABTWJPYBKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.22
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  五羰基溴铼(I) 、 sodium N-(P,P-diphenylphosphinoyl)-P,P-diphenylphosphinimidate 以 甲苯 为溶剂， 以95%的产率得到Na[Re2(CO)6(μ-Ph2P(O)NP(O)Ph2-κ2O)2]
  参考文献：
  名称：

  Spontaneous Formation of an Organometallic−Inorganic Dirhenium Carbonyl Cryptate Encapsulating a Sodium Cation

  摘要：

  The reactions between the rhenium(1) complexes [ReBr(CO)(5)], [Re2Br2(CO)(6)(THF)(2)], and [ReOTf(CO)(5)] and Na[Ph2P(O)NP(O)Ph-2] in toluene and THF under reflux and in dichloromethane at room temperature, respectively, afforded the complex Na[Re-2(CO)(6){mu-Ph2P(O)NP(O)Ph-2-kappa O-2}(3)] in good to medium yields; all X-ray crystallographic study in the solid state revealed that the sodium atom is enclosed in the cage formed by two -Re(CO)(3) fragments joined by three end-bound [Ph2P(O)NP(O)Ph-2] ligands.

  DOI：

  10.1021/om050912f
• 作为产物：
  描述：

  imidotetraphenyldiphosphinic acid 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 以80%的产率得到sodium N-(P,P-diphenylphosphinoyl)-P,P-diphenylphosphinimidate
  参考文献：
  名称：

  Day, Roberta O.; Holmes, Robert R.; Schmidpeter, Alfred, Chemische Berichte, 1991, vol. 124, # 11, p. 2443 - 2448

  摘要：

  DOI：

文献信息

• Organolead(IV) derivatives of oxophosphorus ligands.
  作者：Richard A. Varga、John E. Drake、Cristian Silvestru

  DOI：10.1016/s0022-328x(03)00229-8

  日期：2003.5

  Ph2Pb[(OPPh2)2N]2 (1), Ph2Pb[(OPPh2)(SPPh2)N]2 (2), Me3Pb[(OPPh2)2N] (3) and Ph3Pb[(OPPh2)(SPPh2)N] (4). Attempts to grow crystals of Me3Pb[(OPPh2)2N] (3) led to isolation of Me2Pb[(OPPh2)2N]2 (5), as a result of decomposition. Me3Pb(O2PPh2) (6) was obtained from Me3PbCl and Na(O2PPh2). The compounds were characterized by IR and multinuclear NMR spectroscopy. The molecular structures of 1, 5 and 6 were

  R 4- n PbCl n与Na [（OPPh 2）2 N]或K [（OPPh 2）（SPPh 2）N]的反应可分离出Ph 2 Pb [（OPPh 2）2 N] 2（1） ，Ph 2 Pb [（OPPh 2）（SPPh 2）N] 2（2），Me 3 Pb [（OPPh 2）2 N]（3）和Ph 3 Pb [（OPPh 2）（SPPh 2）N]（第四名）。试图生长Me 3 Pb [（OPPh 2）2 N]（3）晶体的结果是，由于分解，导致Me 2 Pb [（OPPh 2）2 N] 2（5）分离。从Me 3 PbCl和Na（O 2 PPh 2）获得Me 3 Pb（O 2 PPh 2）（6）。通过IR和多核NMR光谱对化合物进行表征。的分子结构1，5和6通过单晶X射线衍射确定。5的晶体在晶胞中包含两个独立的分子。在这两种化合物中，亚氨基二膦基配体均充当单金属双连接单元，从而形成具有扭曲的舟形构型的六元PbO
• Preparation and single-crystal characterization of manganese(II) complexes of dichalcogenoimidodiphosphinato ligands. Monomeric versus dimeric Mn[(OPPh2)(XPPh2)N]2 (X=S, O)
  作者：Ildiko Szekely、Cristian Silvestru*、John E Drake*、Gabor Balazs、Sorin I Farcas、Ionel Haiduc

  DOI：10.1016/s0020-1693(99)00507-1

  日期：2000.3

  Mn[(OPPh2)(SPPh2)N]2 units, with a distorted tetrahedral MnO2S2 core, as a result of monometallic biconnective phosphorus ligands. By contrast, in the crystal of the tetraphenylimidodiphosphinato analogue distinct [Mn(OPPh2)2N}2]2 dimers are present, in which the MnO5 core has a trigonal bipyramidal geometry. The coordination pattern of the four imidodiphosphinato ligands differs. Two of them act as monometallic

  摘要通过MnCl2·4H2O之间的复分解反应制备了Mn [（XPR2）（YPR'2）N] 2（X，Y = O，S; R，R'= Me，Ph）型锰（II）化合物和相应配体的碱性盐。IR数据与去质子化形式的磷配体的配位一致。ESR谱仅对Mn [（OPMe2）（SPPh2）N] 2衍生物表现出分辨的超精细结构。Mn [（OPPh2）（YPPh2）N] 2（Y = O，S）的晶体和分子结构通过X射线衍射法测定。由于单金属双连接磷配体的作用，四苯基硫代亚氨基二膦酸酯衍生物的晶体包含单螺旋双环Mn [（OPPh2）（SPPh2）N] 2单元，其四面体MnO2S2核扭曲。相比之下，在四苯基亚氨基二膦酸酯类似物的晶体中，存在明显的[Mn （OPPh2）2N} 2] 2二聚体，其中MnO5核具有三角双锥几何形状。四个亚氨基二膦酸酯配体的配位方式不同。其中两个充当单金属双连接（螯合）单元，导致六元 P
• Synthesis, spectroscopic characterization, and structural studies of new Cu(I) and Cu(II) complexes containing organophosphorus ligands, and crystal structures of (Ph₃P)₂Cu[S₂PMe₂], (Ph₃P)₂Cu[(OPPh₂)₂N], Cu[(OPPh₂)₂N]₂, and Cu[(OPPh₂)(SPPh₂)N]₂
  作者：Anca Silvestru、Adina Rotar、John E Drake、Michael B Hursthouse、Mark E Light、Sorin I Farcas、Roland Rösler、Cristian Silvestru

  DOI：10.1139/v01-048

  日期：2001.5.1

  The Cu(I) complexes, (Ph₃P)₂CuL (L = [S₂PMe₂]^-, [OSPR₂]^- (R = Me, Ph), [(XPR₂)(YPR'₂)N]^- (X, Y, R, R' = O, O, Ph, Ph; O, S, Ph, Ph; O, S, OEt, Ph; S, S, Me, Me)) and Cu(II) complexes, CuL₂ (L = [(XPR₂)(YPR'₂)N]^- (X, Y, R, R' = O, O, Ph, Ph; O, S, Ph, Ph)), have been prepared. The Cu(I) derivatives were characterized by multinuclear NMR spectroscopy and in two cases by X-ray crystallography. (Ph₃P)₂Cu[S₂PMe₂] (1) crystallizes in the orthorhombic space group P2₁2₁2₁ (No. 19) with cell parameters a = 9.782(2), b = 17.808(4), c = 20.216(4) Å, V = 3521(6) ų and Z = 4, and (Ph₃P)₂Cu[(OPPh₂)₂N] (4) in the triclinic space group P[Formula: see text] (No. 2) with cell parameters a = 9.8079(2), b = 12.9141(3), c = 22.5666(5) Å, α = 75.714(2), β = 79.465(2), γ = 68.2770(8)°, V = 2559.9(1) ų and Z = 2. In both cases the phosphorus ligands are bidentate, thus resulting in monomeric molecules that contain tetrahedral CuP₂S₂ and CuP₂O₂ cores. The molecular structures of two of the Cu(II) derivatives were also determined. Cu[(OPPh₂)₂N]₂ (8) and Cu[(OPPh₂)(SPPh₂)N]₂ (9) crystallize in the triclinic space group P[Formula: see text] (No. 2) with cell parameters a = 8.887(2), b = 10.739(2), c = 12.477(3) Å, α = 77.61(3), β = 76.15(5), γ = 79.46(3)°, V = 1118.3(4) ų and Z = 1 for 8, and a = 9.626(2), b = 14.151(3), c = 24.752(5) Å, α = 88.23(3), β = 79.93(3), γ = 89.77(3)°, V = 3181(1) ų and Z = 3 for 9. The molecule of Cu[(OPPh₂)₂N]₂ (8) has a planar CuO₄ core, while in Cu[(OPPh₂)(SPPh₂)N]₂ (9) both planar and tetrahedral copper cores are observed in a ratio of 1:2.Key words: structure, copper, thiophosphinates, oxo- and thio-imidodiphosphinates

  Cu(I)配合物，(Ph3P)2CuL (L = [S2PMe2]-, [OSPR2]- (R = Me, Ph), [(XPR2)(YPR'2)N]- (X, Y, R, R' = O, O, Ph, Ph; O, S, Ph, Ph; O, S, OEt, Ph; S, S, Me, Me)) 和Cu(II)配合物，CuL2 (L = [(XPR2)(YPR'2)N]- (X, Y, R, R' = O, O, Ph, Ph; O, S, Ph, Ph)) 已经制备。Cu(I)衍生物通过多核NMR光谱和两种情况下的X射线晶体学表征。(Ph3P)2Cu[S2PMe2] (1) 在正交晶系空间群P212121 (No. 19)中结晶，晶胞参数为a = 9.782(2) Å，b = 17.808(4) Å，c = 20.216(4) Å，V = 3521(6) Å3，Z = 4，而(Ph3P)2Cu[(OPPh2)2N] (4) 在三斜晶系空间群P[Formula: see text] (No. 2)中结晶，晶胞参数为a = 9.8079(2) Å，b = 12.9141(3) Å，c = 22.5666(5) Å，α = 75.714(2)°，β = 79.465(2)°，γ = 68.2770(8)°，V = 2559.9(1) Å3，Z = 2。在这两种情况下，磷配体是双齿的，因此得到含有四面体CuP2S2和 O2核的单分子化合物。还确定了两个Cu(II)衍生物的分子结构。Cu[(OPPh2)2N]2 (8) 和Cu[(OPPh2)(SPPh2)N]2 (9) 在三斜晶系空间群P[Formula: see text] (No. 2)中结晶，晶胞参数为a = 8.887(2) Å，b = 10.739(2) Å，c = 12.477(3) Å，α = 77.61(3)°，β = 76.15(5)°，γ = 79.46(3)°，V = 1118.3(4) Å3，Z = 1，对于8，以及a = 9.626(2) Å，b = 14.151(3) Å，c = 24.752(5) Å，α = 88.23(3)°，β = 79.93(3)°，γ = 89.77(3)°，V = 3181(1) Å3，Z = 3，对于9。Cu[(OPPh2)2N]2 (8) 的分子具有平面CuO4核，而在Cu[(OPPh2)(SPPh2)N]2 (9) 中观察到平面和四面体铜核的比例为1:2。关键词：结构，铜，硫代磷酸盐，氧-和硫-咪唑二磷酸酯。
• Probing the local coordination environment and nuclearity of uranyl(vi) complexes in non-aqueous media by emission spectroscopy
  作者：Michael P. Redmond、Stephanie M. Cornet、Sean D. Woodall、Daniel Whittaker、David Collison、Madeleine Helliwell、Louise S. Natrajan

  DOI：10.1039/c0dt01464h

  日期：——

  We describe the synthesis, solid state and solution properties of two families of uranyl(VI) complexes that are ligated by neutral monodentate and anionic bidentate PO, PNH and AsO ligands bearing pendent phenyl chromophores. The uranyl(VI) ions in these complexes possess long-lived photoluminescent LMCT 3Πu excited states, which can be exploited as a sensitive probe of electronic structure, bonding

  我们描述了由中性单齿和阴离子双齿P O，P NH和As O配体带有悬垂苯基发色团连接而成的两个铀酰（VI）配合物家族的合成，固态和溶液性质。双氧铀（VI在这些配合物）离子具有长寿命的光致发光LMCT 3 Π ü激发态，其可被利用作为电子结构，粘合和聚集行为的在非水介质中的灵敏探测器。对于反式-[UO 2 Cl 2（L 2）]（L = Ph 3 PO（1），Ph在3 AsO（ 2）和Ph 3 PNH（ 3））中，CH 2 Cl 2中的发射光谱图指示了在赤道平面上结合的供体原子的强度和铀酰键的强度；随着L供体强度的增加，铀酰LMCT的发射最大值移至较低的能量。流体溶液的发光寿命反映了这些观察结果（0.87–3.46μs），并且对振动和双分子失活特别敏感。在相关阴离子的结构良好定义的络合物家族中，四苯基亚氨基二次膦酸酯（TPIP），单金属络合物[UO 2（TPIP）（thf）]（ 4），[UO 2（TPIP）（Cy
• Exploring the Coordination of Plutonium and Mixed Plutonyl–Uranyl Complexes of Imidodiphosphinates
  作者：Kathryn George、Julie Muller、Laurence Berthon、Claude Berthon、Dominique Guillaumont、Iñigo J. Vitorica-Yrezabal、H. Victoria Stafford、Louise S. Natrajan、Christelle Tamain

  DOI：10.1021/acs.inorgchem.9b00346

  日期：2019.5.20

  The coordination chemistry of plutonium(IV) and plutonium(VI) with the complexing agents tetraphenyl and tetra-isopropyl imidodiphosphinate (TPIP– and TIPIP–) is reported. Treatment of sodium tetraphenylimidodiphosphinate (NaTPIP) and its related counterpart with peripheral isopropyl groups (NaTIPIP) with [NBu4]2[PuIV(NO3)6] yields the respective PuIV complexes [Pu(TPIP)3(NO3)] and [Pu(TIPIP)2(NO3)2]

  据报道，with （IV）和p（VI）与络合剂四苯基和亚氨基二亚膦酸四异丙酯（TPIP –和TIPIP –）的配位化学。用[NBu 4 ] 2 [Pu IV（NO 3）6 ]处理四苯基亚氨基二次膦酸钠（NaTPIP）及其相关的周边外围异丙基（NaTIPIP），得到各自的Pu IV复合物[Pu（TPIP）3（NO 3）]和[Pu（TIPIP）2（NO 3）2 ] + [Pu IV（TIPIP）3（NO 3）]。类似地，NaTPIP和NaTIPIP的与普（VI）的硝酸溶液引线的反应的形成[的PuO 2（HTIPIP）2（H 2 O）] [NO 3 ] 2，其中结合了质子化的二齿TIPIP -配体，和[PuO 2（TPIP）（HTPIP）（NO 3）]，其中质子化的HTPIP配体以单齿方式结合。最后，混合的U（VI）/ Pu（VI）化合物，[（UO 2 / PuO 2）（TPIP）（HTPIP）（NO