[Cu2(dinemac)2(tp)(ClO4)2] | 890738-91-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu2(dinemac)2(tp)(ClO4)2]
• 英文别名: [Cu2(3,10-dimethyl-3,10-dinitro-1,4,8,11-tetraaza cyclotetradecane)2(terephthalate)(ClO4)2]
• CAS: 890738-91-7
• 化学式: C₃₂H₅₆Cl₂Cu₂N₁₂O₂₀
• 分子量: 1126.86
• InChiKey: ROCHTIFLAFZKIM-MOUWEACQSA-J

反应信息

• 作为产物：
  描述：

  [Cu(dinemac)](ClO4)2 、 对苯二甲酸 在 Et₃N 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 以41%的产率得到[Cu2(dinemac)2(tp)(ClO4)2]
  参考文献：
  名称：

  Synthesis, crystal structure and helical ladder-like assembly of a novel terephthalato-bridged binuclear Cu(II) complex: First report on terephthalate bridging under tetraaza macrocyclic environment

  摘要：

  Single crystal X-ray study on a novel terephthalato-(mu(2)-tp)-bridged binuclear Cu(II) tetraaza macrocyclic complex, [Cu-2(dine-mac)(2)(tp)(ClO4)(2)], reveals that the syn-anti disposition of two NO2 groups in the individual dinemac ligand and consequent intermolecular H-bonding between the two successive binuclear entities on both sides results a supramolecular R-2(2) (34) synthon in (011) plane which on further propagation in the same sequence renders two single strand helices connected via tp moiety results a 3-D supramolecular helical ladder-like assembly. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.10.017