(E)-(5-methoxypent-1-en-1-yl)(phenyl)sulfane | 1350624-98-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (E)-(5-methoxypent-1-en-1-yl)(phenyl)sulfane
• CAS: 1350624-98-4
• 化学式: C₁₂H₁₆OS
• 分子量: 208.324
• InChiKey: PPEMUCSMSZKPOH-YRNVUSSQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.72
• 重原子数：
  14.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1-甲氧基-4-戊炔 、 苯硫酚 在 diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh₃)] 作用下， 以 乙醇 为溶剂， 反应 24.0h， 以67%的产率得到(E)-(5-methoxypent-1-en-1-yl)(phenyl)sulfane
  参考文献：
  名称：

  Heterogeneous Hydrothiolation of Alkynes with Thiols Catalyzed by Diphosphino-Functionalized MCM-41 Anchored Rhodium Complex

  摘要：

  A novel diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh3)] was conveniently synthesized by the reaction of diphosphino-functionalized MCM-41 (MCM-41-2P) with RhCl(PPh3)(3). It was found that this rhodium complex is an efficient catalyst for the hydrothiolation of terminal alkynes with thiols and can be recovered and recycled by a simple filtration of the reaction solution and used for at least ten consecutive trials without any decreases in activity.

  DOI：

  10.1007/s10562-011-0732-x