bromo-bis(2,3,4,5,6-pentafluorophenyl)gallane | 147050-21-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bromo-bis(2,3,4,5,6-pentafluorophenyl)gallane
• CAS: 147050-21-3
• 化学式: C₁₂BrF₁₀Ga
• 分子量: 483.743
• InChiKey: IZEXBFFKPIWLNT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  24.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  bromo-bis(2,3,4,5,6-pentafluorophenyl)gallane 在 吡啶 作用下， 以 吡啶 为溶剂， 以75%的产率得到Ga(C₆F₅)2Br*NC₅H₅
  参考文献：
  名称：

  Synthesis and properties of pentafluorophenylgallium derivatives. The preparation of tris(pentafluorophenyl) gallium and its adducts, and of bis(pentafluorophenyl) gallium bromide, pentafluorophenylgallium dibromide, and tetrabutylammonium tetrakis(pentafluorophenyl)gallate

  摘要：

  A complete series of mono-, bis-, tris- and tetrakis-(pentafluorophenyl)gallium compounds has been obtained from the reactions of GaCl3 and GaBr3 With Mg(C6F5)Br. The complexation behaviour of Ga(C6F5)3 . O(C2H5)2 With N-donor molecules has been studied; 1 : 1 adducts with pyridine, diethylamine, tert/butyl amine and aniline as well as the uncomplexed Ga(C6F5)3 and [(n-C4H9)4N][Ga(C6F5)4] have been obtained pure. All the compounds were characterized by NMR spectroscopy, mass spectrometry and elemental analysis, and some IR spectra were recorded.

  DOI：

  10.1016/0022-328x(92)80167-v
• 作为产物：
  描述：

  氯化镓 在 Mg(C₆F₅)Br 作用下， 以 乙醚 、 甲苯 为溶剂， 以21%的产率得到bromo-bis(2,3,4,5,6-pentafluorophenyl)gallane
  参考文献：
  名称：

  Synthesis and properties of pentafluorophenylgallium derivatives. The preparation of tris(pentafluorophenyl) gallium and its adducts, and of bis(pentafluorophenyl) gallium bromide, pentafluorophenylgallium dibromide, and tetrabutylammonium tetrakis(pentafluorophenyl)gallate

  摘要：

  A complete series of mono-, bis-, tris- and tetrakis-(pentafluorophenyl)gallium compounds has been obtained from the reactions of GaCl3 and GaBr3 With Mg(C6F5)Br. The complexation behaviour of Ga(C6F5)3 . O(C2H5)2 With N-donor molecules has been studied; 1 : 1 adducts with pyridine, diethylamine, tert/butyl amine and aniline as well as the uncomplexed Ga(C6F5)3 and [(n-C4H9)4N][Ga(C6F5)4] have been obtained pure. All the compounds were characterized by NMR spectroscopy, mass spectrometry and elemental analysis, and some IR spectra were recorded.

  DOI：

  10.1016/0022-328x(92)80167-v