Pd2(GaCl4)2(mesitylene)2*mesitylene | 1234279-98-1

• 英文名称: Pd2(GaCl4)2(mesitylene)2*mesitylene
• CAS: 1234279-98-1
• 化学式: C₉H₁₂*C₁₈H₂₄Cl₈Ga₂Pd₂
• 分子量: 996.493
• InChiKey: LXFMSMRMLMQMJH-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化镓 、 palladium dichloride 、 均三甲苯 在 biphenyl 作用下， 以 均三甲苯 为溶剂， 以21%的产率得到Pd2(GaCl4)2(mesitylene)2*mesitylene
  参考文献：
  名称：

  Synthesis and characterization of binuclear palladium(I) compounds and the influence of competing arenes

  摘要：

  The binuclear palladium(I) compounds, [Pd(2)(Ga(2)Cl(7))(2)(C(7)H(8))(2)] (1), [Pd(2)(GaCl(4))(2)(C(9)H(12))(2)]center dot C(9)H(12) (2) and [Pd(2)(Ga(2)Cl(7))(2)(C(6)H(5)Cl)(2)] (3), have been prepared from palladium(II) chloride in gallium(III) chloride-arene reaction media. All isolated crystalline solids (1, 2 and 3) have been structurally characterized by single crystal X-ray diffraction and Raman spectroscopy. The results form quantum chemical calculations on the interaction energies of the arenes and the dipalladium unit of these compounds is also presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.011