hydrogen fluoride-chlorine monofluoride complex | 61981-49-5

• 分子结构分类: 无机化合物 - 均质非金属化合物
• 英文名称: hydrogen fluoride-chlorine monofluoride complex
• CAS: 61981-49-5
• 化学式: ClF*FH
• 分子量: 74.4577
• InChiKey: PTBQDFDVBOMBOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.26
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氢氟酸 、 一氟化氯 以 solid matrix 为溶剂， 生成 hydrogen fluoride-chlorine monofluoride complex 、 、 hydrogen fluoride-chlorine monofluoride complex
  参考文献：
  名称：

  固体氩气和氖气中双原子卤素与氟化氢配合物的红外光谱

  摘要：

  DOI：

  10.1021/j100324a016

文献信息

• Photochemical reactions of ClF and BrF with hydrogen in solid argon. Infrared spectra of mixed hydracid dimers
  作者：Rodney D. Hunt、Lester Andrews

  DOI：10.1063/1.453909

  日期：1988.3.15

  Argon diluted samples of H2 and ClF were codeposited at 10 K, and no reaction was observed. Photolysis produced a sharp 2834.5, 2832.5 cm−1 doublet, in agreement with (HF)(HCl) dimer from HF and HCl codeposition experiments. Irradiation at 14–16 K markedly increased the mixed dimer and produced weak monomer and dimer bands of HCl and HF, mixed trimer absorptions, and a sharp band at 3857.9 cm−1 for the Cl--HF radical complex. In similar experiments with HD, two mixed dimers, (HF)(DCl) and (HCl)(DF), were formed; likewise, photolyzing D2 with ClF produced two mixed dimers of the form (DF)(DCl) and (DCl)(DF). In the H2 and BrF system, photolysis produced a sharp absorption at 3814.6 cm−1, in agreement with (HBr)(HF) dimer from HBr and HF codeposition experiments, and a new 3830.5 cm−1 band due to the Br--HF radical complex. In a parallel study with HD, two mixed dimers, (HBr)(DF) and (DBr)(HF), were observed while only one mixed dimer, (DBr)(DF), was formed by BrF and D2. In complementary experiments with H2 and Cl2, (HCl)2 was observed at 2818.1 and 2816.2 cm−1.