Formation of binuclear pyrazolate-bridged palladium carboxylates in the reactions of [Pd(Hdmpz)4](OOCR2) (R = Me, Bu t , Ph) with heterometallic Pd-Co acetate
摘要:
The reactions of [Pd(Hdmpz)(4)](OOCR)(2) (R = Me, Bu (t) , Ph, Hdmpz = 3,5-dimethylpyrazole) with the heterometallic acetate Pd(mu-OOCMe)(4)Co(NCMe) gives pyrazolate-bridged dimers Pd-2(mu-dmpz)(2)(Hdmpz)(2)(OOCR)(2) (R = Me, Bu (t) , Ph), which were characterized by X-ray diffraction.