| 136082-10-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 136082-10-5
• 化学式: C₂₆H₂₆AuP₂Se*F₆Sb
• 分子量: 912.107
• InChiKey: RCVPRJWIGNAJJW-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  7.26
• 重原子数：
  37.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 (二甲基苯基膦)氯化金 、 硒化三苯膦 以 not given 为溶剂， 生成 、 金
  参考文献：
  名称：

  Gold complexes with selenium ligands 3. Cationic gold(I) complexes with phosphine selenide ligands

  摘要：

  The cationic gold complexes [(Ph3PSe)2Au]+ (1) and [(Ph3P)Au(SePPh3)]+ (2) are obtained in good yield as their SbF6- salts from the appropriate reaction between LAuCl, AgSbF6 and L'. Attempts to prepare other cationic complexes [L"Au(SePPh3)]+ (where L" is a phosphine other than PPh3) led to some decomposition to metallic gold, and concomitantly poorly characterised or uncharacterised products, but the isolation in low yield of [(Ph3P)Au(SePPhMe2)]+ (3) from a corresponding reaction with Ph3PSe and PhMe2PAuCl demonstrates that selenium is exchanged between phosphines. Complexes 1 and 3 were characterised by X-ray structure determination; complex 2 is severely disordered.

  DOI：

  10.1016/s0020-1693(00)86824-3