dimethylaminotris[tris(dimethylamino)phosphoranilideneamino]phosphonium hydroxide | 195212-09-0

• 分子结构分类: 有机化合物
• 英文名称: dimethylaminotris[tris(dimethylamino)phosphoranilideneamino]phosphonium hydroxide
• 英文别名: Dimethylamino-tris[[tris(dimethylamino)-lambda5-phosphanylidene]amino]phosphanium;hydroxide；dimethylamino-tris[[tris(dimethylamino)-λ5-phosphanylidene]amino]phosphanium;hydroxide
• CAS: 195212-09-0
• 化学式: C₂₀H₆₀N₁₃P₄*HO
• 分子量: 623.686
• InChiKey: OPTMXNISOMWRDI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.94
• 重原子数：
  38
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  70.5
• 氢给体数：
  1
• 氢受体数：
  14

文献信息

• Poly (alkylene oxide) prepared in the presence of a phosphazenium salt or compound
  申请人：Mitsui Chemicals, Inc.

  公开号：US20030225244A1

  公开（公告）日：2003-12-04

  The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): 1 wherein n stands for an integer of from 1 to 8, Z n− represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).

  本发明提供了一种新型盐，可用作有机反应中的活性物种，其化学式（1）如下：1其中n为1至8的整数，Zn-表示活性氢化合物的n价阴离子，a、b、c和d分别表示正整数，Rs表示相同或不同的碳氢基团。还公开了一种简单高效的方法，通过在化学式（1）所表示的盐存在下聚合烷基氧化物化合物，以制备聚（烷基氧化物）。
• PROCESS FOR PRODUCING POLY (ALKYLENE OXIDE) IN THE PRESENCE OF A PHOSPHAZENIUM SALT OR COMPOUND
  申请人：——

  公开号：US20030105361A1

  公开（公告）日：2003-06-05

  The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): 1 wherein n stands for an integer of from 1 to 8, Z n− represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).

  本发明提供了一种新型盐，可用作有机反应中的活性物种，其化学式表示为（1）：1其中n为1至8的整数，Zn-表示活性氢化合物的n价阴离子，a、b、c和d各代表正整数，Rs表示相同或不同的碳氢基团。还公开了一种简单高效的方法，通过在化学式（1）所表示的盐的存在下聚合烷氧化物化合物来制备聚（烷氧基）化合物。
• Phosphazenium salt and preparation process thereof, and process for producing poly(alkylene oxide)
  申请人：MITSUI TOATSU CHEMICALS, INC.

  公开号：EP0791600A1

  公开（公告）日：1997-08-27

  The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): wherein n stands for an integer of from 1 to 8, Zn- represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).

  本发明提供了一种新型盐，可作为有机反应中的活性物质，其化学式如下（1）： 其中 n 代表 1 至 8 的整数，Zn- 代表活性氢化合物的 n 价阴离子，a、b、c 和 d 各代表一个正整数，Rs 代表相同或不同的烃基。本发明还公开了一种简单高效的聚环氧亚烷烃生产工艺，该工艺是在化学式（1）所代表的盐存在下，通过聚合环氧亚烷烃化合物来生产聚环氧亚烷烃。
• Process for producing poly(alkylene oxide) and product thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1243608A2

  公开（公告）日：2002-09-25

  The present invention provides a novel salt useful as an active species in an organic reaction namely a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the present of the salt.

  本发明提供了一种新型盐，可作为有机反应中的活性物质，即在盐的存在下，通过聚合环氧亚烷基化合物来生产聚环氧亚烷基化合物的简单而高效的工艺。
• (METH)ACYLATE-GRAFTED POLYETHER POLYOL, AND PROCESS FOR PRODUCTION AND USE THEREOF
  申请人：Mitsui Chemicals Polyurethanes, Inc.

  公开号：EP1939231A1

  公开（公告）日：2008-07-02

  A (meth)acrylate-grafted polyether polyol produced by reacting 40 to 95 parts by weight of a polyoxyalkylene polyol and 5 to 60 parts by weight of a vinyl monomer, both relative to 100 parts by weight of the sum total of the polyoxyalkylene polyol and the vinyl monomer, and 0.1 to 5 moles of an alkyl peroxide as a radical initiator per mole of the hydroxyl group in the polyoxyalkylene polyol, wherein the polyoxyalkylene polyol has a hydroxyl number of 25 mg KOH/g or less, and the vinyl monomer contains a (meth)acrylate and/or a hydroxyl-containing (meth)acrylate in an amount of 50% by weight or higher. The (meth)acrylate-grafted polyether polyol is excellent in colorless-transparency, compatibility, mechanical strength, weather resistance, and blending resistance, and therefore is useful as a raw material for a polyurethane resin cured article.

  一种(甲基)丙烯酸酯接枝的聚醚多元醇，它是由 40 至 95 份(重量)聚氧 乙烯多元醇和 5 至 60 份(重量)乙烯基单体(两者相对于 100 份(重量)聚氧 乙烯多元醇和乙烯基单体的总和)，以及 0.1至5摩尔的过氧化烷基作为自由基引发剂，其中聚氧亚烷基多元醇的羟基数为25毫克KOH/克或更少，乙烯基单体中(甲基)丙烯酸酯和/或含羟基的(甲基)丙烯酸酯的含量为50%(重量)或更高。(甲基)丙烯酸酯接枝的聚醚多元醇在无色透明性、相容性、机械强度、耐候性和耐混合性方面表现优异，因此可用作聚氨酯树脂固化物的原料。