雷酸苯酯 | 67249-97-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 雷酸苯酯
• 英文名称: phenyl fulminate
• 英文别名: Isocyanooxybenzene
• CAS: 67249-97-2
• 化学式: C₇H₅NO
• 分子量: 119.123
• InChiKey: FTSOEAJNEQSYBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  雷酸苯酯 、 molybdenum hexacarbonyl 在 十二/十四烷基二甲基氧化胺 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  羰基钼配合物中官能化异腈的反应性

  摘要：

  研究了钼的β-苯氧基-和β-硫代苯氧基-乙腈配合物的消除-加成反应；消除途径被20到50之间的因子加速，而络合作用使乙烯基异腈具有很强的亲电性。

  DOI：

  10.1039/c39890001231
• 作为产物：
  描述：

  二苯基碘酰氯 以 丙酮 为溶剂， 反应 7.0h， 生成 雷酸苯酯
  参考文献：
  名称：

  Reactive nitrogenous molecules from Meldrum's acid derivatives, pyrrole-2,3-diones, and isoxazolones

  摘要：

  DOI：

  10.1021/jo00189a025

文献信息

• Metallkomplexe funktioneller Isocyanide
  作者：Wolf Peter Fehlhammer、Gerhard Zinner、Maria Bakola-Christianopoulou

  DOI：10.1016/0022-328x(87)80021-9

  日期：1987.9

  The metallo-nitrile ylides (M  Cr, W) react with CS2, methyl isocyanate and phenyl isothiocyanate regio- and site-specifically to give carbenoid five-membered heterocycles containing the structural element of a vinyl analogous phosphine oxide (sulfide). In addition, an (exoS-coordinated isomer was observed in one case. the exo-sulfur atom has been methylated and has been introduced into a platinum(II)

  金属腈（MCr，W）与CS 2，异氰酸甲酯和异硫氰酸苯基在位置和位置上发生特定反应，生成含有类乙烯基氧化膦（硫化物）结构元素的类胡萝卜素五元杂环。此外，（外切在一种情况下，观察到S-协调异构体。该外型-硫原子被甲基化的和已被引入铂（II）络合物。
• Compounds and Methods for Inhibiting the Interaction of BCL Proteins with Binding Partners
  申请人：Castro Alfredo C.

  公开号：US20110213145A1

  公开（公告）日：2011-09-01

  The invention relates to isoxazolidine containing compounds that bind to bcl proteins and inhibit Bcl function. The compounds may be used for treating and modulating disorders associated with hyperproliferation, such as cancer.

  本发明涉及含有异氧杂环丙氨酸的化合物，这些化合物与bcl蛋白结合并抑制Bcl功能。这些化合物可用于治疗和调节与过度增殖有关的疾病，如癌症。
• AROMATIC DICYANATE COMPOUNDS WITH HIGH ALIPHATIC CARBON CONTENT
  申请人：Mullins Michael J.

  公开号：US20110009559A1

  公开（公告）日：2011-01-13

  Aromatic dicyanate compounds which comprise aliphatic moieties having at least about six carbon atoms and resins and thermoset products based on these compounds.
• ETHYLENICALLY UNSATURATED MONOMERS COMPRISING ALIPHATIC AND AROMATIC MOIETIES
  申请人：Hefner, JR. Robert E.

  公开号：US20110009560A1

  公开（公告）日：2011-01-13

  Polymerizable monomers comprising at least one 1- or 2-propylene moiety and further comprising both aromatic moieties and additional aliphatic moieties and polymerizable mixtures, resins and thermoset products based on these monomers.
• INTEGRATED CAPSTAN AND APPARATUS FOR SCREEN TESTING AN OPTICAL FIBER
  申请人：Corning Incorporated

  公开号：US20160356669A1

  公开（公告）日：2016-12-08

  An integrated capstan for use in fiber processing and testing apparatus. The integrated capstan features a fiber-engaging material that provides a contact surface for fibers. The hardness of the contact surface is controlled to minimize transfer of stress to the fibers to prevent damage to fiber coatings or fiber splice junctions during conveyance or screen testing of fibers during production. The fiber-engaging material includes a resilient material and an optional capping layer. The resilient material may be a lightly crosslinked polyurethane gel. Capping layers include polymers formed by UV curing of aliphatic urethane diacrylate compounds or moisture curing of diisocyanate compounds.