| 1354790-74-1

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 1354790-74-1；1354790-75-2
• 化学式: C₅₀H₆₄N₂NiO₂
• 分子量: 783.76
• InChiKey: UZEUAGSIEPBXCB-QYMJJMKGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 not given 为溶剂， 以0%的产率得到((CH₃)3CC₆H₃(OCH₃)C₆(CH₃)4C₆H₂(C(CH₃)3)(O)CHNC₆H₃(CH(CH₃)2)2)Ni(NC₅H₅)(CH₃)
  参考文献：
  名称：

  Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases

  摘要：

  Dinickel complexes supported by terphenyl ligands appended with phenoxy and imine donors were synthesized. Full substitution of the central arene blocks rotation around the aryl aryl bond and allows for the isolation of atropisomers. The reported complexes perform ethylene polymerization in the presence of amines. The inhibiting effect of polar additives is up to 250 times lower for the syn isomer than the anti isomer. Comparisons with mononuclear systems indicate that the proximity of the metal centers leads to the observed inhibitory effect on the deactivation of the catalysts.

  DOI：

  10.1021/ja210990t
• 作为产物：
  描述：

  ((CH₃)3CC₆H₃(OCH₃)C₆(CH₃)4C₆H₂(C(CH₃)3)(O)CHNC₆H₃(CH(CH₃)2)2)Ni(NC₅H₅)(CH₃) 以 not given 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases

  摘要：

  Dinickel complexes supported by terphenyl ligands appended with phenoxy and imine donors were synthesized. Full substitution of the central arene blocks rotation around the aryl aryl bond and allows for the isolation of atropisomers. The reported complexes perform ethylene polymerization in the presence of amines. The inhibiting effect of polar additives is up to 250 times lower for the syn isomer than the anti isomer. Comparisons with mononuclear systems indicate that the proximity of the metal centers leads to the observed inhibitory effect on the deactivation of the catalysts.

  DOI：

  10.1021/ja210990t

文献信息

• MULTI-METALLIC ORGANOMETALLIC COMPLEXES, AND RELATED POLYMERS, COMPOSITIONS, METHODS AND SYSTEMS
  申请人：RADLAUER Madalyn

  公开号：US20130066029A1

  公开（公告）日：2013-03-14

  Multi-metallic organometallic complexes that allow performance of olefin based reaction and in particular polymerization of olefins to produce polyolefin polymers, and related methods and systems are described.

  描述了一种多金属有机金属配合物，可用于进行基于烯烃的反应，特别是进行烯烃的聚合以生产聚烯烃聚合物，以及相关的方法和系统。