(2-(p-tolylazo)-1-N-salicylidene phenylamine(-2H))palladium(II) | 1043962-86-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: (2-(p-tolylazo)-1-N-salicylidene phenylamine(-2H))palladium(II)
• CAS: 1043962-86-2
• 化学式: C₂₀H₁₅N₃OPd
• 分子量: 419.779
• InChiKey: XBJQEUFISSTFJC-KUUGMZOISA-M

反应信息

• 作为反应物：
  描述：

  (2-(p-tolylazo)-1-N-salicylidene phenylamine(-2H))palladium(II) 、 间氯过氧苯甲酸 以 二氯甲烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis, structure and reactivity of azosalophen complexes of palladium

  摘要：

  The ligands 2-(arylazo)-1-N-salicylidene phenylamine, H2Lsal, (where H represents the dissociable protons upon complexation) afford stable orthopalladated complexes, [(L-sal)Pd], upon treatment with Na-2[PdCl4]. The dinegative anionic (L-sal)(2-) ligands bind Pd(II) in a tetradentate (C, N, N, O) fashion with a distorted square planar geometry. The newly synthesized palladium complexes underwent oxygen insertion into the Pd-C bond with mCPBA (m-chloroperbenzoic acid) or TBHP (terbutylhydroperoxide)/[VO(acac)(2)] leading to the formation of stable azosalophen complexes of Pd(II) with the (O, N, N, O) coordination mode of the oxygenated ligand. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.028
• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 N-[2-(p-tolylazo)phenyl]salicylideneamine 以 乙醇 为溶剂， 以57%的产率得到(2-(p-tolylazo)-1-N-salicylidene phenylamine(-2H))palladium(II)
  参考文献：
  名称：

  Synthesis, structure and reactivity of azosalophen complexes of palladium

  摘要：

  The ligands 2-(arylazo)-1-N-salicylidene phenylamine, H2Lsal, (where H represents the dissociable protons upon complexation) afford stable orthopalladated complexes, [(L-sal)Pd], upon treatment with Na-2[PdCl4]. The dinegative anionic (L-sal)(2-) ligands bind Pd(II) in a tetradentate (C, N, N, O) fashion with a distorted square planar geometry. The newly synthesized palladium complexes underwent oxygen insertion into the Pd-C bond with mCPBA (m-chloroperbenzoic acid) or TBHP (terbutylhydroperoxide)/[VO(acac)(2)] leading to the formation of stable azosalophen complexes of Pd(II) with the (O, N, N, O) coordination mode of the oxygenated ligand. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.028