5-(4-methoxycarbonylphenyl)-10,15,20-tris(4-pyridyl)porphyrinatomagnesium | 1452580-85-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 5-(4-methoxycarbonylphenyl)-10,15,20-tris(4-pyridyl)porphyrinatomagnesium
• CAS: 1452580-85-6
• 化学式: C₄₃H₂₇MgN₇O₂
• 分子量: 698.038
• InChiKey: KIXJDZIPXPOZLX-CHDIQBLZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  5-(4-methoxycarbonylphenyl)-10,15,20-tris(4-pyridyl)porphyrinatomagnesium 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以15 mg的产率得到5-(4-methoxycarbonylphenyl)-10,15,20-tris(4-pyridyl)porphine
  参考文献：
  名称：

  Two-Photon Oxygen Sensing with Quantum Dot-Porphyrin Conjugates

  摘要：

  Supramolecular assemblies of a quantum dot (QD) associated to palladium(II) porphyrins have been developed to detect oxygen (pO(2)) in organic solvents. Palladium porphyrins are sensitive in the 0-160 Torr range, making them ideal phosphors for in vivo biological oxygen quantification. Porphyrins with meso pyridyl substituents bind to the surface of the QD to produce self-assembled nanosensors. Appreciable overlap between QD emission and porphyrin absorption features results in efficient Forster resonance energy transfer (FRET) for signal transduction in these sensors. The QD serves as a photon antenna, enhancing porphyrin emission under both one- and two-photon excitation, demonstrating that QD-palladium porphyrin conjugates may be used for oxygen sensing over physiological oxygen ranges.

  DOI：

  10.1021/ic4011168
• 作为产物：
  描述：

  4-[二(1H-吡咯-2-基)甲基]吡啶 在 乙基溴化镁 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 5.0h， 生成 5-(4-methoxycarbonylphenyl)-10,15,20-tris(4-pyridyl)porphyrinatomagnesium
  参考文献：
  名称：

  Two-Photon Oxygen Sensing with Quantum Dot-Porphyrin Conjugates

  摘要：

  Supramolecular assemblies of a quantum dot (QD) associated to palladium(II) porphyrins have been developed to detect oxygen (pO(2)) in organic solvents. Palladium porphyrins are sensitive in the 0-160 Torr range, making them ideal phosphors for in vivo biological oxygen quantification. Porphyrins with meso pyridyl substituents bind to the surface of the QD to produce self-assembled nanosensors. Appreciable overlap between QD emission and porphyrin absorption features results in efficient Forster resonance energy transfer (FRET) for signal transduction in these sensors. The QD serves as a photon antenna, enhancing porphyrin emission under both one- and two-photon excitation, demonstrating that QD-palladium porphyrin conjugates may be used for oxygen sensing over physiological oxygen ranges.

  DOI：

  10.1021/ic4011168