C4H4NO2Ag*Ph3P | 1159614-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: C4H4NO2Ag*Ph3P
• CAS: 1159614-03-5
• 化学式: C₂₂H₁₉AgNO₂P
• 分子量: 468.24
• InChiKey: LNBCDPZJJGQSIV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-silver(I) succinimide 、 三苯基膦 以 二氯甲烷 为溶剂， 以94%的产率得到C4H4NO2Ag*Ph3P
  参考文献：
  名称：

  Synthesis and characterization of organophosphine/phosphite stabilized N-silver(I) succinimide: crystal structure of [(Ph3P)3·AgNC4H4O2]

  摘要：

  Six organophosphite stabilized N-silver(I) succinimide complexes of the type Ln center dot AgNC4H4O2 (L=PPh3; n=1, 2a; n =2, 2b; n =3, 2c; L=P(OEt)(3); n=1, 2d; n=2, 2e; n =3, 2f) have been prepared by reacting (AgNC4O2], which can be synthesized from succinimide and excessive Ag2O in boiling water, with triphenylphospine or triethylphosphite in dichloromethane under a nitrogen atmosphere. These complexes were obtained in high yield and characterized by elemental analysis. H-1, C-13(H) NMR, IR spectroscopy and thermal analysis (TG and DSC). The molecular structure of 2c has been determined by X-ray single crystal analysis, in which the silver atom is in distorted tetrahedral geometry. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.02.021