bis(cyclopentadienyl)bis(1,1,3,3-tetramethylurea)ytterbium(II) | 170168-69-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(cyclopentadienyl)bis(1,1,3,3-tetramethylurea)ytterbium(II)
• 英文别名: cyclopenta-1,3-diene;1,1,3,3-tetramethylurea;ytterbium(2+)
• CAS: 170168-69-1
• 化学式: C₂₀H₃₄N₄O₂Yb
• 分子量: 535.556
• InChiKey: KEKADJTVGXQQFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (bicyclopentadienyl)Yb*(tetrahydrofuran)2 、 1,1,3,3-四甲基脲 以 正己烷 为溶剂， 以97%的产率得到bis(cyclopentadienyl)bis(1,1,3,3-tetramethylurea)ytterbium(II)
  参考文献：
  名称：

  Synthesis and characterization of a tetramethylurea adduct of a biscyclopentadienyl ytterbium(II) complex: X-ray crystal structure of YbCp2·2TMU

  摘要：

  The complex YbCp(2) . 3TMU (TMU=1,1,3,3-tetramethylurea) has been synthesized by addition of (CH3)(2)NCON(CH3)2 to YbCp(2) . THF, obtained by reduction of YbCp(2)Cl . THF with sodium naphthalenide. The characterization was done by metal analysis and IR and H-1 nuclear magnetic resonance spectroscopies. Orange-reddish crystals of YbCp(2) . 2TMU, were obtained by slow evaporation of a benzene solution of YbCp(2) . 3TMU. The compound crystallizes in the monoclinic space group C2/c with four molecules in a unit cell of dimensions a = 14.892(4) Angstrom, b = 12.792(2) Angstrom, c = 12.484(4) Angstrom, beta = 99.37(1)degrees and V = 2346(1)Angstrom(3) (R = 0.033, R(w) = 0.037 for 125 parameters and 2127 reflections with F-o>3 sigma(F-o)).

  DOI：

  10.1016/0925-8388(94)07036-9