methaneylpropenoic acid 2-hydroxy-3-butoxypropyl ester | 13282-83-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: methaneylpropenoic acid 2-hydroxy-3-butoxypropyl ester
• 英文别名: methylpropaneenoic acid 2-hydroxy-3-butoxypropyl ester；(methyl)propenoic acid 3-butoxy-2-hydroxypropyl ester；methylpropeneic acid 2-hydroxy-3-butoxypropyl ester；methylpropenoic acid 2-hydroxy-3-butoxypropyl ester；2-hydroxy-3-butoxypropyl methylpropenoate；2-hydroxy-3-butoxypropyl methacrylate；(3-Butoxy-2-hydroxypropyl) 2-methylprop-2-enoate
• CAS: 13282-83-2
• 化学式: C₁₁H₂₀O₄
• 分子量: 216.277
• InChiKey: DQOKNNHAZSNFOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  sodium;3-butoxy-2-hydroxypropan-1-olate 、 甲基丙烯酰氯 以18%的产率得到
  参考文献：
  名称：

  KIMSANOV B. X.; XABIBULAEVA O. K., DOKL. AKAD. FANXOI PCC TOCHIKISTON, DOKL. AN TADZHSSR, 1978, 21, HO 1, 39+

  摘要：

  DOI：

文献信息

• HYDROXYPHENYL PHENANTHROLINES AS POLYMERIZABLE BLOCKERS OF HIGH ENERGY LIGHT
  申请人：Johnson & Johnson Vision Care, Inc.

  公开号：US20190002459A1

  公开（公告）日：2019-01-03

  Described are high energy light blocking compounds and ophthalmic devices containing the compounds. In particular, described are hydroxyphenyl phenanthroline structures with polymerizable functionality that block high energy light and are visibly transparent. The hydroxyphenyl phenanthroline structures can be incorporated into ophthalmic devices, such as hydrogel contact lenses, to protect eyes from high energy light radiation.

  描述了高能量光阻挡化合物和含有这些化合物的眼科器械。具体来说，描述了含有可聚合功能的羟基苯基菲啰啉结构，这些结构可以阻挡高能量光并且具有可见透明性。这些羟基苯基菲啰啉结构可以被应用到眼科器械中，比如水凝胶隐形眼镜，以保护眼睛免受高能量光辐射的伤害。
• Polycarbonate-modified urethane acrylate adhesive
  申请人：NEGAMI CHEMICAL INDUSTRIAL CO LTD

  公开号：EP0142228A1

  公开（公告）日：1985-05-22

  @ There is disclosed a polycarbonate-modified urethane acrylate adhesive comprising: [A] a polycarbonate-modified urethane acrylate oligomer which is a reaction product of: (1) 100 parts by weight of a hydroxyl group-containing (meth)acrylate represented by the formula [I]: wherein R' represents a hydrogen atom or a methyl group; R2 represents a substituted or unsubstituted hydrocarbon group ora group with a valence ofa having the hydrocarbon groups, which may be the same or different, bonded to each other with an ether bond or an ester bond and also having at least one hydroxyl group; and is an integer of 1 to 3, (2) 10 to 4,500 parts by weight of a bifunctional organic component comprising: (a) a polycarbonate diol represented by the formula [II]: wherein R3, which may be the same or different, represents divalent hydrocarbon groups having 2 to 15 carbon atoms or divalent groups comprising the hydrocarbon groups, which may be the same or different, bonded to each other with an ether bond or an ester bond, which hydrocarbon groups may be substituted with a halogen atom; and n is a number of 1 to 60 on the average, and (b) a bifunctional compound containing active hydrogen atom selected from the group consisting of alkylene glycol, its oxyacid ester, polyether diol, heterocyclic diol containing ether bond, polyester diol, thioether glycol and dithiol, containing 1 to 100 % by weight of(a) based on thetotal amount of the component (2); and (3) 0.005 to 50 parts by weight of an alkoxy silane containing amino group or its partial hydrolyzed condensate, and (4) a polyisocyanate containing 70 to 100 % of isocyanato groups of the theoretical amount reactive with the total active hydrogen atoms contained in the above components (1) to (3), and [B] a reactive diluent in an amount of 5 to 1,000 % by weight of the [A].

  @本发明公开了一种聚碳酸酯改性聚氨酯丙烯酸酯粘合剂，包括 [A] 聚碳酸酯改性聚氨酯丙烯酸酯低聚物，它是以下物质的反应产物： (1) 100 份(重量)由式[I]代表的含羟基的(甲基)丙烯酸酯： 其中 R'代表氢原子或甲基；R2 代表取代或未取代的烃基或具有 a 价的烃基，这些烃基可以相同或不同，彼此以醚键或酯键结合，并至少具有一个羟基；和 是 1 至 3 的整数、 (2) 10 至 4,500 重量份的双官能团有机组分，包括： (a) 由式[II]表示的聚碳酸酯二元醇： 其中 R3（可以相同或不同）代表具有 2 至 15 个碳原子的二价烃基或由烃基组成 的二价基团（可以相同或不同），彼此以醚键或酯键结合，这些烃基可以被卤素原子 取代；n 是平均为 1 至 60 的数字，以及 (b) 含有活性氢原子的双官能团化合物，选自由烷二醇、其氧酸酯、聚醚二 醇、含醚键的杂环二醇、聚酯二醇、硫醚二醇和二硫醇组成的组，以组分 （2）的总量为基准，含 1%至 100%（按重量计）的（a）；以及 (3) 0.005 至 50 重量份的含氨基的烷氧基硅烷或其部分水解缩合物，和 (4) 一种多异氰酸酯，含有与上述组分（1）至（3）所含总活性氢原子反应的理论量为 70%至 100%的异氰酸酯基团，以及 [B] 一种活性稀释剂，其用量为[A]重量的 5%至 1,000%。
• Polymer composition having improved durability and method relating thereto
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0407858A1

  公开（公告）日：1991-01-16

  The present invention relates to polymer compositions having improved durability. More specifically, the composition and method of this invention is directed to the use of an olefin additive, particularly an acrylate, to substantially reduce delamination and premature aging in polymer materials comprising substantially immiscible polymer components.

  本发明涉及具有更好耐久性的聚合物组合物。更具体地说，本发明的组合物和方法涉及使用烯烃添加剂，特别是丙烯酸酯，以大幅减少由基本不相溶的聚合物成分组成的聚合物材料中的分层和过早老化现象。
• HIGHLY HEAT-RESISTANT, NEGATIVE-TYPE PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Asahi Kasei EMD Corporation

  公开号：EP1536286A1

  公开（公告）日：2005-06-01

  Disclosed is a negative type photosensitive resin composition comprising (A) a polyamide having a photopolymerizable unsaturated double bond, (B) a monomer having a photopolymerizable unsaturated double bond, (C) a photopolymerization initiator and (D) a melamine resin.

  本发明公开了一种负型感光树脂组合物，该组合物包括：(A) 具有可进行光聚合的不饱和双键的聚酰胺；(B) 具有可进行光聚合的不饱和双键的单体；(C) 光聚合引发剂；(D) 三聚氰胺树脂。
• POLYAMIDE
  申请人：Asahi Kasei EMD Corporation

  公开号：EP1775316A1

  公开（公告）日：2007-04-18

  A polyamide having a structure represented by the chemical formula (1): wherein m and n represent an integer satisfying m≥1, n≥1, 2≤(m+n)≤150, 0.3≤m/(m+n)≤0.9, R1 and R2 represent at least one monovalent organic group containing a photopolymerizable unsaturated bond, X1 represents at least one tetravalent aromatic group, X2 represents at least one trivalent aromatic group, Y1 and Y2 represent at least one divalent organic group, and Z represents at least one monovalent organic group selected from mono-substituted amino and imido groups.

  一种聚酰胺，其结构由化学式（1）表示： 其中 m 和 n 代表满足 m≥1, n≥1, 2≤(m+n)≤150, 0.3≤m/(m+n)≤0.9、R1 和 R2 代表至少一个含有可光聚合不饱和键的一价有机基团，X1 代表至少一个四价芳香基团，X2 代表至少一个三价芳香基团，Y1 和 Y2 代表至少一个二价有机基团，Z 代表至少一个选自单取代氨基和亚氨基的一价有机基团。