[Co(III)(N,N'-disalicylidene-1,2-phenylendiamine dianion)(morpholine)2](ClO4) | 354156-18-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Co(III)(N,N'-disalicylidene-1,2-phenylendiamine dianion)(morpholine)2](ClO4)
• CAS: 354156-18-6
• 化学式: C₂₈H₃₂CoN₄O₄*ClO₄
• 分子量: 647.03
• InChiKey: BVVXOLNPNNJXGE-YSVHZKDNSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吗啉 、 N,N'-二水杨醛缩-1,2-苯二胺 、 sodium perchlorate 、 cobalt(II) diacetate tetrahydrate 在 air 作用下， 以 甲醇 、 丙酮 为溶剂， 以63%的产率得到[Co(III)(N,N'-disalicylidene-1,2-phenylendiamine dianion)(morpholine)2](ClO4)
  参考文献：
  名称：

  Synthesis and spectroscopic characterization of [CoIII(salophen)(amine)2]ClO4 (amine=morpholine, pyrrolidine, and piperidine) complexes. The crystal structures of [CoIII(salophen)(morpholine)2]ClO4 and [CoIII(salophen)(pyrrolidine)2]ClO4

  摘要：

  Three Co(III) complexes of the type [Co(salophen)(amine)(2)]ClO4, salophen = N,N ' -disalicylidene-1,2-phenylendiamine dianion and amine = morpholine (1), pyrrolidine (2), and piperidine (3), have been synthesized and characterized by elemental analysis, IR, UV-Vis, H-1, and C-13 NMR spectroscopy. [Co(salophen)(morpholine)(2)]ClO4 (1) and [Co(salophen)(pyrrolidine)(2)]ClO4 (2) have been studied by X-ray diffraction. Compound 1 crystallizes in ribbons of complexes and perchlorates held together by weak N-H . .O and C-H . . .O hydrogen bonds between morpholines and perchlorates. The latter also interconnect the chains to a 3D network. Some minor pi-pi interactions exist. Compound 2 crystallizes as endless chains of complexes linked by weak C-H . . .O hydrogen bonds to the disordered perchlorates. The pyrrolidine moiety is turned by 90 degrees with respect to 1 and forms intramolecular N-H . . .O hydrogen bonds, The coordination polyhedra of 1 and 2 possess C-s symmetry, and the salophens are not planar in either of them. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0378-3758(01)00095-7