| 1150566-00-9

• 分子结构分类: 有机化合物
• CAS: 1150566-00-9
• 化学式: C₂₃H₁₇CdN₄O₄*Cl
• 分子量: 561.275
• InChiKey: LFCUPIOFYXEHFW-PNYOAKSVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  aqueous cadmium chloride 、 N'1-(2-hydroxybenzylidene)-N'2-(2-oxo-1,2-diphenylethylidene)oxalohydrazide 以 乙醇 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis, spectral, and biological studies of some metal(II) complexes with benzil salicylaldehyde acyldihydrazones

  摘要：

  Complexes of the general formula [M(Bsodh)] Cl and [M(Bsmdh)] Cl, where M = Co(II), Ni( II), Cu(II), Zn(II,) and Cd(II) (HBsodh = benzil salicylaldehyde oxalic acid dihydrazone and HBsmdh = benzil salicylaldehyde malonic acid dihydrazone) were synthesized and characterized by elemental analyses, molar conductance, magnetic moments, electronic, ESR, infrared spectra, and X-ray diffraction studies. The complexes are stable solids insoluble in common organic solvents and 1 : 1 electrolytes. The magnetic moments and electronic spectra reveal a square-planar geometry for [M(Bsodh)] Cl and a six-coordinate octahedral geometry for [M(Bsmdh)] Cl. The HBsodh ligand bonds to the metal ion via one > C=O, two > C=N-, and one deprotonated phenolate group, whereas HBsmdh bonds through three > C=O, two > C=N-, and one phenolate group. The lattice parameters for [Co(Bsodh)]Cl and [Ni(Bsmdh)]Cl correspond to tetragonal and orthorhombic crystal lattices, respectively. ESR spectral data indicate the presence of an unpaired electron in d(x2-y2) of the Cu2+ ion. The ligands, as well as their metal complexes, show significant antibacterial activity against Bacillus subtilis and Pseudomonas fluorescens.

  DOI：

  10.1134/s1070328408040064