2-(2-chlorotetrafluoroethanesulfinyl)-6-phenylhex-1-en-3-one | 1184977-66-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-chlorotetrafluoroethanesulfinyl)-6-phenylhex-1-en-3-one
• CAS: 1184977-66-9
• 化学式: C₁₄H₁₃ClF₄O₂S
• 分子量: 356.769
• InChiKey: KNEZMLMAVGAFLN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-chloro-1,1,2,2-tetrafluoroethanesulfinyl chloride 、 以65%的产率得到2-(2-chlorotetrafluoroethanesulfinyl)-6-phenylhex-1-en-3-one
  参考文献：
  名称：

  The addition of perfluoroalkanesulfinyl chlorides to alkoxyallenes

  摘要：

  The addition reaction of perfluoroalkanesulfinyl chlorides to alkoxyallenes was achieved under mild conditions. Two kinds of perfluoroalkyl alkenyl sulfoxides, beta-alkoxyvinyl perfluoroalkyl sulfoxides and alpha-perfluoroalkanesulfinyl enones or enals, were obtained selectively depending on the structure of alkoxyallenes. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2008.12.007