ethyl-(4-phenyl-but-2-enyl)-ether | 56184-17-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl-(4-phenyl-but-2-enyl)-ether
• 英文别名: Aethyl-(4-phenyl-but-2-enyl)-aether；4-Ethoxybut-2-enylbenzene
• CAS: 56184-17-9
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: WRCCPGCJDBNSCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  烯丙苯 、 1,4-diethoxy-2-butene 在 RuCl₂(3-tert-butyl-1-indenylidene)(PCy₃)₂ 作用下， 以 二氯甲烷 为溶剂， 生成 ethyl-(4-phenyl-but-2-enyl)-ether
  参考文献：
  名称：

  Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity

  摘要：

  We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)(2) in which R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidene catalysts were analyzed by means of IR, elemental analysis, NMR and single crystal X-Ray diffraction analysis. Furthermore, the catalytic performance of these new complexes was examined in different metathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activity in comparison with the commercially available catalyst 3a. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2015.04.054

文献信息

• A Convenient Method for the Transformation of Allylstannanes to Alcohols, Ethers, Esters, and Amines
  作者：Takeshi Takeda、Tomoya Inoue、Tooru Fujiwara

  DOI：10.1246/cl.1988.985

  日期：1988.6.5

  Allylstannanes were easily oxidized with copper(II) bromide in the presence of water, alcohols, and sodium acetate to give the corresponding allylic alcohols, ethers, and acetates, respectively. The allylic amines were also obtained by the successive treatments of allylstannanes with copper(II) bromide and amines.

  在水、醇和乙酸钠的存在下，烯丙基锡烷很容易被溴化铜 (II) 氧化，分别得到相应的烯丙醇、醚和乙酸酯。烯丙基胺也是通过用溴化铜 (II) 和胺连续处理烯丙基锡烷而获得的。
• Ganushchak,N.I. et al., Soviet progress in chemistry, 1975, vol. 41, # 5, p. 53 - 55
  作者：Ganushchak,N.I. et al.

  DOI：——

  日期：——