[Li(N,N-di(2-pyridylmethyl)glycine)(H2O)]*H2O | 618093-29-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Li(N,N-di(2-pyridylmethyl)glycine)(H2O)]*H2O
• 英文别名: [Li(bpg)(H2O)]*H2O
• CAS: 618093-29-1
• 化学式: C₁₄H₁₆LiN₃O₃*H₂O
• 分子量: 299.256
• InChiKey: REKVDSMECKPEMX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  copper(II) nitrate trihydrate 、 [Li(N,N-di(2-pyridylmethyl)glycine)(H2O)]*H2O 以 乙醇 为溶剂， 以90%的产率得到[copper(II)(2-(bis((pyridin-2-yl)methyl)amino)acetate)]nitrate monohydrate
  参考文献：
  名称：

  Synthesis, characterization and properties of copper(II) complexes containing N,N-di-(2-pyridylmethyl)-glycine and alanine

  摘要：

  The multidentate ligands N,N-di-(2-pyridylmethyl)-glycine (bpg) and N,N-di-(2-pyridylmethyl)-alanine (bpa) were synthesized as their lithium salts and X-ray structures of these solved. Copper(II) complexes of these ligands have been prepared and structurally characterized. X-ray structures of compounds [Li(bpg)(H2O)].H2O (1) and [Li(bpa)(H2O)].H2O (2) shown the Li(I) ions adopt a distorted trigonal bipyrimidal geometry whereas in the Cu(II) compounds [Cu(bpg)](NO3).H2O (3) and [Cu(bpa)](SO3CF3).H2O (6) the Cu(II) ions are in an approximate square pyramidal geometry. The ligand chelates the copper ion in a tetradentate fashion with two pyridine N atoms, one tertiary imine N atom occupying the equatorial positions, and one carboxylato O atom occupying an axial position. The last equatorial position is occupied by the O atom from the carboxylate group of the neighboring molecule and thus forms a covalently bonded zig-zag chain, coordination polymer. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00083-5