tetraphenylantimony 1-adamantanecarboxylate benzene monosolvate | 1229245-34-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylantimony 1-adamantanecarboxylate benzene monosolvate
• CAS: 1229245-34-4
• 化学式: C₆H₆*C₃₅H₃₅O₂Sb
• 分子量: 687.525
• InChiKey: NOOOWZMQDCHHJF-LXSFRHIZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.96
• 重原子数：
  44.0
• 可旋转键数：
  6.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  triphenylantimony bis(1-adamantanecarboxylate) 、 pentaphenylantimony 、 苯 以 苯 为溶剂， 以88%的产率得到tetraphenylantimony 1-adamantanecarboxylate benzene monosolvate
  参考文献：
  名称：

  Synthesis and structure of tetraphenylantimony 1-adamantanecarboxylate and triphenylantimony bis(1-adamantanecarboxylate)

  摘要：

  Reaction of pentaphenylantimony with triphenylantimony bis(1-adamantylcarboxylate) yielded the solvate of tetraphenylantimony 1-adamantylcarboxylate with benzene. Triphenylantimony bis(1-adamantylcarboxylate) was prepared from triphenylantimony and 1-adamantylcarboxylic acid in the presence of hydrogen peroxide in ether. X-ray studies showed that in the first and in the second product antimony atom has the distorted trigonal bipyramide coordination (OSbO and CSbO trans-angles are 179.42A degrees and 174.58A degrees, respectively). Sb-O interatomic distances are 2.154 and 2.202 , respectively. The carbonyl group oxygen atom is coordinated with the central atom, Sba <-O interatomic distances are 2.570 and 3.396 , respectively.

  DOI：

  10.1134/s1070363209100107